Reactivity of the [Mo(3)(μ(3)-S)(μ(2)-S(2))(3)Br(6)](2-) anion toward the imidodiphosphinochalcogenido ligands [N(QPPh(2))(2)]- (Q = S, Se): Synthesis and characterization of [Mo(3)(μ(3)-S)(μ(2)-S(2))(3){N(QPPh(2))(2)}(3)]Br

Virginie Béreau, Christopher G. Pernin, James A Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

Reactions of imidodiphosphinochalcogenido ligands [N(QPPh2)2]- (Q = S, Se) with [Mo33-S)(μ2-S2)3-Br6]2- (1) afford the first Mo complexes of such ligands: [Mo(μ3-S)(μ2-S2)3{N(SPPh2)2}3]Br (2) and [Mo33-S)(μ2-S)3{N(SePPh2)2}3]Br (3). In these complexes the [Mo33-S)(μ2-S2)3]4+ core is maintained and three [N(QPPh2)2]- ligands are bound to the Mo atoms in a Q,Q'-bidentate fashion.

Original languageEnglish (US)
Pages (from-to)854-856
Number of pages3
JournalInorganic Chemistry
Volume39
Issue number4
DOIs
StatePublished - Feb 21 2000

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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