Abstract
Reactions of imidodiphosphinochalcogenido ligands [N(QPPh2)2]- (Q = S, Se) with [Mo3(μ3-S)(μ2-S2)3-Br6]2- (1) afford the first Mo complexes of such ligands: [Mo(μ3-S)(μ2-S2)3{N(SPPh2)2}3]Br (2) and [Mo3(μ3-S)(μ2-S)3{N(SePPh2)2}3]Br (3). In these complexes the [Mo3(μ3-S)(μ2-S2)3]4+ core is maintained and three [N(QPPh2)2]- ligands are bound to the Mo atoms in a Q,Q'-bidentate fashion.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 854-856 |
| Number of pages | 3 |
| Journal | Inorganic Chemistry |
| Volume | 39 |
| Issue number | 4 |
| DOIs | |
| State | Published - Feb 21 2000 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry
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Dive into the research topics of 'Reactivity of the [Mo(3)(μ(3)-S)(μ(2)-S(2))(3)Br(6)](2-) anion toward the imidodiphosphinochalcogenido ligands [N(QPPh(2))(2)]- (Q = S, Se): Synthesis and characterization of [Mo(3)(μ(3)-S)(μ(2)-S(2))(3){N(QPPh(2))(2)}(3)]Br'. Together they form a unique fingerprint.Datasets
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CCDC 142953: Experimental Crystal Structure Determination
Béreau, V. (Contributor), Pernin, C. G. (Creator) & Ibers, J. A. (Creator), Cambridge Crystallographic Data Centre, 2000
DOI: 10.5517/cc4srd1, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4srd1&sid=DataCite
Dataset
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CCDC 142952: Experimental Crystal Structure Determination
Béreau, V. (Contributor), Pernin, C. G. (Contributor) & Ibers, J. A. (Contributor), Cambridge Crystallographic Data Centre, 2000
DOI: 10.5517/cc4src0, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4src0&sid=DataCite
Dataset
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CCDC 142954: Experimental Crystal Structure Determination
Béreau, V. (Contributor), Pernin, C. G. (Creator) & Ibers, J. A. (Creator), Cambridge Crystallographic Data Centre, 2000
DOI: 10.5517/cc4srf2, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/cc4srf2&sid=DataCite
Dataset