Abstract
Reactions of imidodiphosphinochalcogenido ligands [N(QPPh2)2]- (Q = S, Se) with [Mo3(μ3-S)(μ2-S2)3-Br6]2- (1) afford the first Mo complexes of such ligands: [Mo(μ3-S)(μ2-S2)3{N(SPPh2)2}3]Br (2) and [Mo3(μ3-S)(μ2-S)3{N(SePPh2)2}3]Br (3). In these complexes the [Mo3(μ3-S)(μ2-S2)3]4+ core is maintained and three [N(QPPh2)2]- ligands are bound to the Mo atoms in a Q,Q'-bidentate fashion.
Original language | English (US) |
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Pages (from-to) | 854-856 |
Number of pages | 3 |
Journal | Inorganic Chemistry |
Volume | 39 |
Issue number | 4 |
DOIs | |
State | Published - Feb 21 2000 |
ASJC Scopus subject areas
- Physical and Theoretical Chemistry
- Inorganic Chemistry