Reactivity of the [Mo(3)(μ(3)-S)(μ(2)-S(2))(3)Br(6)](2-) anion toward the imidodiphosphinochalcogenido ligands [N(QPPh(2))(2)]- (Q = S, Se): Synthesis and characterization of [Mo(3)(μ(3)-S)(μ(2)-S(2))(3){N(QPPh(2))(2)}(3)]Br

Virginie Béreau; Christopher G. Pernin; James A Ibers

doi:10.1021/ic9907056

Reactivity of the [Mo(3)(μ(3)-S)(μ(2)-S(2))(3)Br(6)](2-) anion toward the imidodiphosphinochalcogenido ligands [N(QPPh(2))(2)]^- (Q = S, Se): Synthesis and characterization of [Mo(3)(μ(3)-S)(μ(2)-S(2))(3){N(QPPh(2))(2)}(3)]Br

Virginie Béreau, Christopher G. Pernin, James A Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

18 Scopus citations

Abstract

Reactions of imidodiphosphinochalcogenido ligands [N(QPPh₂)₂]^- (Q = S, Se) with [Mo₃(μ₃-S)(μ₂-S₂)₃-Br₆]^2- (1) afford the first Mo complexes of such ligands: [Mo(μ₃-S)(μ₂-S₂)₃{N(SPPh₂)₂}₃]Br (2) and [Mo₃(μ₃-S)(μ₂-S)₃{N(SePPh₂)₂}₃]Br (3). In these complexes the [Mo₃(μ₃-S)(μ₂-S₂)₃]⁴⁺ core is maintained and three [N(QPPh₂)₂]^- ligands are bound to the Mo atoms in a Q,Q'-bidentate fashion.

Original language	English (US)
Pages (from-to)	854-856
Number of pages	3
Journal	Inorganic Chemistry
Volume	39
Issue number	4
DOIs	https://doi.org/10.1021/ic9907056
State	Published - Feb 21 2000

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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@article{47dfa010305249d0b5743ed2e94dcb3b,

title = "Reactivity of the [Mo(3)(μ(3)-S)(μ(2)-S(2))(3)Br(6)](2-) anion toward the imidodiphosphinochalcogenido ligands [N(QPPh(2))(2)]- (Q = S, Se): Synthesis and characterization of [Mo(3)(μ(3)-S)(μ(2)-S(2))(3){N(QPPh(2))(2)}(3)]Br",

abstract = "Reactions of imidodiphosphinochalcogenido ligands [N(QPPh2)2]- (Q = S, Se) with [Mo3(μ3-S)(μ2-S2)3-Br6]2- (1) afford the first Mo complexes of such ligands: [Mo(μ3-S)(μ2-S2)3{N(SPPh2)2}3]Br (2) and [Mo3(μ3-S)(μ2-S)3{N(SePPh2)2}3]Br (3). In these complexes the [Mo3(μ3-S)(μ2-S2)3]4+ core is maintained and three [N(QPPh2)2]- ligands are bound to the Mo atoms in a Q,Q'-bidentate fashion.",

author = "Virginie B{\'e}reau and Pernin, {Christopher G.} and Ibers, {James A}",

year = "2000",

month = feb,

day = "21",

doi = "10.1021/ic9907056",

language = "English (US)",

volume = "39",

pages = "854--856",

journal = "Inorganic Chemistry",

issn = "0020-1669",

publisher = "American Chemical Society",

number = "4",

}

Reactivity of the [Mo(3)(μ(3)-S)(μ(2)-S(2))(3)Br(6)](2-) anion toward the imidodiphosphinochalcogenido ligands [N(QPPh(2))(2)]^- (Q = S, Se) : Synthesis and characterization of [Mo(3)(μ(3)-S)(μ(2)-S(2))(3){N(QPPh(2))(2)}(3)]Br. / Béreau, Virginie; Pernin, Christopher G.; Ibers, James A.

In: Inorganic Chemistry, Vol. 39, No. 4, 21.02.2000, p. 854-856.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Reactivity of the [Mo(3)(μ(3)-S)(μ(2)-S(2))(3)Br(6)](2-) anion toward the imidodiphosphinochalcogenido ligands [N(QPPh(2))(2)]- (Q = S, Se)

T2 - Synthesis and characterization of [Mo(3)(μ(3)-S)(μ(2)-S(2))(3){N(QPPh(2))(2)}(3)]Br

AU - Béreau, Virginie

AU - Pernin, Christopher G.

AU - Ibers, James A

PY - 2000/2/21

Y1 - 2000/2/21

N2 - Reactions of imidodiphosphinochalcogenido ligands [N(QPPh2)2]- (Q = S, Se) with [Mo3(μ3-S)(μ2-S2)3-Br6]2- (1) afford the first Mo complexes of such ligands: [Mo(μ3-S)(μ2-S2)3{N(SPPh2)2}3]Br (2) and [Mo3(μ3-S)(μ2-S)3{N(SePPh2)2}3]Br (3). In these complexes the [Mo3(μ3-S)(μ2-S2)3]4+ core is maintained and three [N(QPPh2)2]- ligands are bound to the Mo atoms in a Q,Q'-bidentate fashion.

AB - Reactions of imidodiphosphinochalcogenido ligands [N(QPPh2)2]- (Q = S, Se) with [Mo3(μ3-S)(μ2-S2)3-Br6]2- (1) afford the first Mo complexes of such ligands: [Mo(μ3-S)(μ2-S2)3{N(SPPh2)2}3]Br (2) and [Mo3(μ3-S)(μ2-S)3{N(SePPh2)2}3]Br (3). In these complexes the [Mo3(μ3-S)(μ2-S2)3]4+ core is maintained and three [N(QPPh2)2]- ligands are bound to the Mo atoms in a Q,Q'-bidentate fashion.

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