Abstract
(Chemical Equation Presented) Third time's the charm! The structure of the phosphonate antibiotic A53868, first isolated in 1983 from Streptomyces luridus, has proven quite elusive. Originally reported as 1 and later revised to 2, the actual structure of the compound is the unusual dehydro aminophosphonic acid 3.
Original language | English (US) |
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Pages (from-to) | 9089-9092 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 46 |
Issue number | 47 |
DOIs | |
State | Published - 2007 |
Keywords
- Antibiotics
- Biosynthesis
- NMR spectroscopy
- Phosphonate
- Structure elucidation
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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Dive into the research topics of 'Reassignment of the structure of the antibiotic A53868 reveals an unusual amino dehydrophosphonic acid'. Together they form a unique fingerprint.Datasets
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CCDC 671780: Experimental Crystal Structure Determination
Whitteck, J. T. (Creator), Ni, W. (Creator), Griffin, B. M. (Creator), Eliot, A. C. (Creator), Thomas, P. M. (Creator), Kelleher, N. L. (Creator), Metcalf, W. W. (Creator) & Van Der Donk, W. A. (Creator), Cambridge Crystallographic Data Centre, 2008
DOI: 10.5517/ccqk1bm, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccqk1bm&sid=DataCite
Dataset