Reduction of a Tetrafluoroterephthalonitrile-β-Cyclodextrin Polymer to Remove Anionic Micropollutants and Perfluorinated Alkyl Substances from Water

Max J. Klemes, Yuhan Ling, Casey Ching, Congyue Wu, Leilei Xiao, Damian E. Helbling*, William R. Dichtel

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

29 Scopus citations

Abstract

Organic micropollutants (MPs) are anthropogenic substances that contaminate water resources at trace concentrations. Many MPs, including per- and polyfluorinated alkyl substances (PFASs), have come under increased scrutiny because of their environmental persistence and association with various health problems. A β-cyclodextrin polymer linked with tetrafluoroterephthalonitrile (TFN-CDP) has high affinity for cationic and many neutral MPs from contaminated water because of anionic groups incorporated during the polymerization. But TFN-CDP does not bind many anionic MPs strongly, including anionic PFASs. To address this shortcoming, we reduced the nitrile groups in TFN-CDP to primary amines, which reverses its affinity towards charged MPs. TFN-CDP exhibits adsorption distribution coefficients (log KD values) of 2–3 for cationic MPs and −0.5–1.5 for anionic MPs, whereas the reduced TFN-CDP exhibits log KD values of −0.5–1.5 for cationic MPs and 2–4 for anionic MPs, with especially high affinity towards anionic PFASs. Kinetic studies of the removal of 10 anionic PFASs at environmentally relevant concentrations showed 80–98 % removal of all contaminants after 30 min and was superior to commercial granular activated carbon. These findings demonstrate the scope and tunability of CD-based adsorbents derived from a single polymerization and the promise of novel adsorbents constructed from molecular receptors.

Original languageEnglish (US)
Pages (from-to)12049-12053
Number of pages5
JournalAngewandte Chemie - International Edition
Volume58
Issue number35
DOIs
StatePublished - Jan 1 2019

Keywords

  • PFAS
  • adsorbents
  • cyclodextrin
  • micropollutants
  • water treatment

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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