Reprocessable Polyhydroxyurethane Network Composites

Effect of Filler Surface Functionality on Cross-link Density Recovery and Stress Relaxation

Xi Chen, Lingqiao Li, Tong Wei, David C. Venerus, John M Torkelson*

*Corresponding author for this work

Research output: Contribution to journalArticle

8 Citations (Scopus)

Abstract

Conventional polymer network composites cannot be recycled for high-value applications because of the presence of permanent covalent cross-links. We have developed reprocessable polyhydroxyurethane network nanocomposites using silica nanoparticles with different surface functionalities as reinforcing fillers. The property recovery after reprocessing is a function of the interaction between the filler surface and the network matrix during the network rearrangement process. When nonreactive silica nanoparticles lacking significant levels of surface functional groups are used at 4 wt % (2 vol %) loading, the resulting network composite exhibits substantial enhancement in mechanical properties relative to the neat network and based on values of rubbery plateau modulus is able to fully recover its cross-link density after a reprocessing step. When nanoparticles have surface functional groups that can participate in dynamic chemistries with the reprocessable network matrix, reprocessing leads to losses in mechanical properties associated with cross-link density at potential use temperatures, along with faster rates and lower apparent activation energies of stress relaxation at elevated temperature. This work reveals the importance of appropriate filler selection when polymer network composites are designed with dynamic covalent bonds to achieve both mechanical reinforcement and excellent reprocessability, which are needed for the development of recyclable polymer network composites for advanced applications.

Original languageEnglish (US)
Pages (from-to)2398-2407
Number of pages10
JournalACS Applied Materials and Interfaces
Volume11
Issue number2
DOIs
StatePublished - Jan 16 2019

Fingerprint

Stress relaxation
Fillers
Recovery
Polymers
Composite materials
Nanoparticles
Silicon Dioxide
Functional groups
Silica
Mechanical properties
Covalent bonds
Nanocomposites
Reinforcement
Activation energy
Temperature

Keywords

  • covalent adaptable network composites
  • polymer-filler interfaces
  • reprocessability
  • stress relaxation
  • surface functionality

ASJC Scopus subject areas

  • Materials Science(all)

Cite this

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title = "Reprocessable Polyhydroxyurethane Network Composites: Effect of Filler Surface Functionality on Cross-link Density Recovery and Stress Relaxation",
abstract = "Conventional polymer network composites cannot be recycled for high-value applications because of the presence of permanent covalent cross-links. We have developed reprocessable polyhydroxyurethane network nanocomposites using silica nanoparticles with different surface functionalities as reinforcing fillers. The property recovery after reprocessing is a function of the interaction between the filler surface and the network matrix during the network rearrangement process. When nonreactive silica nanoparticles lacking significant levels of surface functional groups are used at 4 wt {\%} (2 vol {\%}) loading, the resulting network composite exhibits substantial enhancement in mechanical properties relative to the neat network and based on values of rubbery plateau modulus is able to fully recover its cross-link density after a reprocessing step. When nanoparticles have surface functional groups that can participate in dynamic chemistries with the reprocessable network matrix, reprocessing leads to losses in mechanical properties associated with cross-link density at potential use temperatures, along with faster rates and lower apparent activation energies of stress relaxation at elevated temperature. This work reveals the importance of appropriate filler selection when polymer network composites are designed with dynamic covalent bonds to achieve both mechanical reinforcement and excellent reprocessability, which are needed for the development of recyclable polymer network composites for advanced applications.",
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Reprocessable Polyhydroxyurethane Network Composites : Effect of Filler Surface Functionality on Cross-link Density Recovery and Stress Relaxation. / Chen, Xi; Li, Lingqiao; Wei, Tong; Venerus, David C.; Torkelson, John M.

In: ACS Applied Materials and Interfaces, Vol. 11, No. 2, 16.01.2019, p. 2398-2407.

Research output: Contribution to journalArticle

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