Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

Zhijie Chen, Penghao Li, Xuan Zhang, Peng Li, Megan C. Wasson, Timur Islamoglu, J Fraser Stoddart, Omar k Farha

Research output: Contribution to journalArticle

2 Citations (Scopus)

Abstract

Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.

Original languageEnglish (US)
Pages (from-to)2900-2905
Number of pages6
JournalJournal of the American Chemical Society
Volume141
Issue number7
DOIs
StatePublished - Feb 20 2019

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Sorption
Metals
Water
Ligands
Steam
Water vapor
Hysteresis

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Cite this

Chen, Zhijie ; Li, Penghao ; Zhang, Xuan ; Li, Peng ; Wasson, Megan C. ; Islamoglu, Timur ; Stoddart, J Fraser ; Farha, Omar k. / Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption. In: Journal of the American Chemical Society. 2019 ; Vol. 141, No. 7. pp. 2900-2905.
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Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption. / Chen, Zhijie; Li, Penghao; Zhang, Xuan; Li, Peng; Wasson, Megan C.; Islamoglu, Timur; Stoddart, J Fraser; Farha, Omar k.

In: Journal of the American Chemical Society, Vol. 141, No. 7, 20.02.2019, p. 2900-2905.

Research output: Contribution to journalArticle

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AU - Chen, Zhijie

AU - Li, Penghao

AU - Zhang, Xuan

AU - Li, Peng

AU - Wasson, Megan C.

AU - Islamoglu, Timur

AU - Stoddart, J Fraser

AU - Farha, Omar k

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