Abstract
Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.
Original language | English (US) |
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Pages (from-to) | 2900-2905 |
Number of pages | 6 |
Journal | Journal of the American Chemical Society |
Volume | 141 |
Issue number | 7 |
DOIs | |
State | Published - Feb 20 2019 |
Funding
O.K.F. gratefully acknowledges support from the Defense Threat Reduction Agency (HDTRA1-18-1-0003). This work made use of the EPIC facility of Northwestern University’s NUANCE Center, which has received support from the Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF NNCI-1542205); the MRSEC program (NSF DMR-1720139) at the Materials Research Center; the International Institute for Nanotechnology (IIN); the Keck Foundation; and the State of Illinois, through the IIN. This work made use of the IMSERC at Northwestern University, which has received support from the NSF (CHE-1048773 and DMR0521267); SHyNE Resource (NSF NNCI-1542205); the State of Illinois; and IIN. P.L. and J.F.S. acknowledge the Joint Center of Excellence in Integrated Nano-Systems (JCIN) at King Abdulaziz City for Science and Technology (KACST) and Northwestern University (NU).
ASJC Scopus subject areas
- Catalysis
- General Chemistry
- Biochemistry
- Colloid and Surface Chemistry
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CCDC 1885985: Experimental Crystal Structure Determination
Chen, Z. (Creator), Li, P. (Creator), Zhang, X. (Creator), Li, P. (Creator), Wasson, M. C. (Creator), Islamoglu, T. (Creator), Stoddart, J. F. (Creator) & Farha, O. K. (Creator), Cambridge Crystallographic Data Centre, 2019
DOI: 10.5517/ccdc.csd.cc219j74, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc219j74&sid=DataCite
Dataset
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CCDC 1885984: Experimental Crystal Structure Determination
Chen, Z. (Creator), Li, P. (Creator), Zhang, X. (Creator), Li, P. (Creator), Wasson, M. C. (Creator), Islamoglu, T. (Creator), Stoddart, J. F. (Creator) & Farha, O. K. (Creator), Cambridge Crystallographic Data Centre, 2019
DOI: 10.5517/ccdc.csd.cc219j63, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc219j63&sid=DataCite
Dataset
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CCDC 1885986: Experimental Crystal Structure Determination
Chen, Z. (Creator), Li, P. (Creator), Zhang, X. (Creator), Li, P. (Creator), Wasson, M. C. (Creator), Islamoglu, T. (Creator), Stoddart, J. F. (Creator) & Farha, O. K. (Creator), Cambridge Crystallographic Data Centre, 2019
DOI: 10.5517/ccdc.csd.cc219j85, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccdc.csd.cc219j85&sid=DataCite
Dataset