Abstract
Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 2900-2905 |
| Number of pages | 6 |
| Journal | Journal of the American Chemical Society |
| Volume | 141 |
| Issue number | 7 |
| DOIs | |
| State | Published - Feb 20 2019 |
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ASJC Scopus subject areas
- Catalysis
- Chemistry(all)
- Biochemistry
- Colloid and Surface Chemistry
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Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption. / Chen, Zhijie; Li, Penghao; Zhang, Xuan; Li, Peng; Wasson, Megan C.; Islamoglu, Timur; Stoddart, J Fraser; Farha, Omar k.
In: Journal of the American Chemical Society, Vol. 141, No. 7, 20.02.2019, p. 2900-2905.Research output: Contribution to journal › Article
TY - JOUR
T1 - Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption
AU - Chen, Zhijie
AU - Li, Penghao
AU - Zhang, Xuan
AU - Li, Peng
AU - Wasson, Megan C.
AU - Islamoglu, Timur
AU - Stoddart, J Fraser
AU - Farha, Omar k
PY - 2019/2/20
Y1 - 2019/2/20
N2 - Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.
AB - Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.
UR - http://www.scopus.com/inward/record.url?scp=85061537747&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=85061537747&partnerID=8YFLogxK
U2 - 10.1021/jacs.8b13710
DO - 10.1021/jacs.8b13710
M3 - Article
VL - 141
SP - 2900
EP - 2905
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 7
ER -