Reverse order-disorder transition of Janus particles confined in two dimensions

Yihao Liang, Boran Ma, Monica Olvera De La Cruz*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Janus particles with different patch sizes, confined to two dimensions, generate a series of patterns of interest to the field of nanoscience. Here we observe reverse melting, where for some densities the system melts under cooling. For a broad range of hydrophobic patch sizes (60°<θ0<90°), a reentrant transition from solid to liquid and then to an ordered phase emerges as temperature (T) decreases due to the formation of rhombus chains at low T. This reentrant phase has pseudo long-range orientational order but short-range translational order, similar to a hexatic phase. Our work provides guidelines to study the melting and assembly of Janus particles in two dimensions, as well as mechanisms to generate phases with specific symmetry.

Original languageEnglish (US)
Article number062607
JournalPhysical Review E
Volume103
Issue number6
DOIs
StatePublished - Jun 2021

ASJC Scopus subject areas

  • Statistical and Nonlinear Physics
  • Statistics and Probability
  • Condensed Matter Physics

Fingerprint

Dive into the research topics of 'Reverse order-disorder transition of Janus particles confined in two dimensions'. Together they form a unique fingerprint.

Cite this