Reversible insertion of carbon dioxide into Pt(ii)-hydroxo bonds

Tracy L. Lohr, Warren E. Piers*, Masood Parvez

*Corresponding author for this work

Research output: Contribution to journalArticle

13 Scopus citations

Abstract

The reactivity of three monomeric diimine Pt(ii) hydroxo complexes, (NN)Pt(OH)R (NN = bulky diimine ligand; R = OH, 1-OH; R = C6H 5, 1-Ph; R = CH3, 1-Me) towards carbon dioxide has been investigated. Insertion into the Pt-OH bonds was found to be facile and reversible at low temperature for all compounds; the reaction with bis-hydroxide 1-OH gives an isolable κ2-carbonato compound 2, with elimination of water.

Original languageEnglish (US)
Pages (from-to)14742-14748
Number of pages7
JournalDalton Transactions
Volume42
Issue number41
DOIs
StatePublished - Nov 7 2013

ASJC Scopus subject areas

  • Inorganic Chemistry

Fingerprint Dive into the research topics of 'Reversible insertion of carbon dioxide into Pt(ii)-hydroxo bonds'. Together they form a unique fingerprint.

Cite this