Reversible interconversion of homochiral triangular macrocycles and helical coordination polymers

Jungseok Heo; You Moon Jeon; Chad A. Mirkin

doi:10.1021/ja0716812

Reversible interconversion of homochiral triangular macrocycles and helical coordination polymers

Jungseok Heo, You Moon Jeon, Chad A. Mirkin^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

237 Scopus citations

Abstract

The self-assembly of homochiral salen-based 60° corner building blocks and Cu²⁺ ions results in either a homochiral molecular triangle or a homochiral helix depending on solvent ratio (MeOH/pyridine). The process is reversible, and each compound has been characterized by a single-crystal X-ray diffraction study.

Original language	English (US)
Pages (from-to)	7712-7713
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	129
Issue number	25
DOIs	https://doi.org/10.1021/ja0716812
State	Published - Jun 27 2007

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja0716812

Cite this

@article{9c491edf797b4f8786823f2c713145bd,

title = "Reversible interconversion of homochiral triangular macrocycles and helical coordination polymers",

abstract = "The self-assembly of homochiral salen-based 60° corner building blocks and Cu2+ ions results in either a homochiral molecular triangle or a homochiral helix depending on solvent ratio (MeOH/pyridine). The process is reversible, and each compound has been characterized by a single-crystal X-ray diffraction study.",

author = "Jungseok Heo and Jeon, {You Moon} and Mirkin, {Chad A.}",

year = "2007",

month = jun,

day = "27",

doi = "10.1021/ja0716812",

language = "English (US)",

volume = "129",

pages = "7712--7713",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "25",

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T1 - Reversible interconversion of homochiral triangular macrocycles and helical coordination polymers

AU - Heo, Jungseok

AU - Jeon, You Moon

AU - Mirkin, Chad A.

PY - 2007/6/27

Y1 - 2007/6/27

N2 - The self-assembly of homochiral salen-based 60° corner building blocks and Cu2+ ions results in either a homochiral molecular triangle or a homochiral helix depending on solvent ratio (MeOH/pyridine). The process is reversible, and each compound has been characterized by a single-crystal X-ray diffraction study.

AB - The self-assembly of homochiral salen-based 60° corner building blocks and Cu2+ ions results in either a homochiral molecular triangle or a homochiral helix depending on solvent ratio (MeOH/pyridine). The process is reversible, and each compound has been characterized by a single-crystal X-ray diffraction study.

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U2 - 10.1021/ja0716812

DO - 10.1021/ja0716812

M3 - Article

C2 - 17539639

AN - SCOPUS:34347237540

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JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

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ER -

Reversible interconversion of homochiral triangular macrocycles and helical coordination polymers

Abstract

ASJC Scopus subject areas

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CCDC 655070: Experimental Crystal Structure Determination

CCDC 655071: Experimental Crystal Structure Determination

CCDC 655072: Experimental Crystal Structure Determination

Cite this

Reversible interconversion of homochiral triangular macrocycles and helical coordination polymers

Abstract

ASJC Scopus subject areas

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Other files and links

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Datasets

CCDC 655070: Experimental Crystal Structure Determination

CCDC 655071: Experimental Crystal Structure Determination

CCDC 655072: Experimental Crystal Structure Determination

Cite this