[Rh(η4-((η5-C5H4)OCH2CH2P(C6H5)2)2Fe)]BF4: An Olefin Hydrogenation Catalyst and the First Rhodium(I) cis-Phosphine—cis-Ether Complex Characterized by Single-Crystal X-ray Diffraction Methods

Alan M. Allgeier; Elizabeth T. Singewald; Chad A Mirkin; Charlotte L. Stern

doi:10.1021/om00020a005

[Rh(η⁴-((η⁵-C₅H₄)OCH₂CH₂P(C₆H₅)₂)₂Fe)]BF₄: An Olefin Hydrogenation Catalyst and the First Rhodium(I) cis-Phosphine—cis-Ether Complex Characterized by Single-Crystal X-ray Diffraction Methods

Alan M. Allgeier, Elizabeth T. Singewald, Chad A Mirkin^*, Charlotte L. Stern

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

The synthesis, reactivity, and characterization of [Rh(η⁴-((η⁵-C₅H₄)OCH₂CH₂P(C₆H₅)₂)₂Fe)]BF₄ (1) is reported. Compound 1 is the first example of a crystallographically characterized Rh(I) complex with a ligand array comprised exclusively of phosphine–ether moieties. The labile ethers in 1 render it susceptible to a variety of ligand substitution reactions and make it an olefin hydrogenation catalyst even in weakly coordinating solvents.

Original language	English (US)
Pages (from-to)	2928-2930
Number of pages	3
Journal	Organometallics
Volume	13
Issue number	8
DOIs	https://doi.org/10.1021/om00020a005
State	Published - Aug 1 1994

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Organic Chemistry
Inorganic Chemistry

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@article{f665d2f424a5400abb34c6503c840f7d,

title = "[Rh(η4-((η5-C5H4)OCH2CH2P(C6H5)2)2Fe)]BF4: An Olefin Hydrogenation Catalyst and the First Rhodium(I) cis-Phosphine—cis-Ether Complex Characterized by Single-Crystal X-ray Diffraction Methods",

abstract = "The synthesis, reactivity, and characterization of [Rh(η4-((η5-C5H4)OCH2CH2P(C6H5)2)2Fe)]BF4 (1) is reported. Compound 1 is the first example of a crystallographically characterized Rh(I) complex with a ligand array comprised exclusively of phosphine–ether moieties. The labile ethers in 1 render it susceptible to a variety of ligand substitution reactions and make it an olefin hydrogenation catalyst even in weakly coordinating solvents.",

author = "Allgeier, {Alan M.} and Singewald, {Elizabeth T.} and Mirkin, {Chad A} and Stern, {Charlotte L.}",

year = "1994",

month = aug,

day = "1",

doi = "10.1021/om00020a005",

language = "English (US)",

volume = "13",

pages = "2928--2930",

journal = "Organometallics",

issn = "0276-7333",

publisher = "American Chemical Society",

number = "8",

}

[Rh(η⁴-((η⁵-C₅H₄)OCH₂CH₂P(C₆H₅)₂)₂Fe)]BF₄: An Olefin Hydrogenation Catalyst and the First Rhodium(I) cis-Phosphine—cis-Ether Complex Characterized by Single-Crystal X-ray Diffraction Methods. / Allgeier, Alan M.; Singewald, Elizabeth T.; Mirkin, Chad A et al.
In: Organometallics, Vol. 13, No. 8, 01.08.1994, p. 2928-2930.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - [Rh(η4-((η5-C5H4)OCH2CH2P(C6H5)2)2Fe)]BF4

T2 - An Olefin Hydrogenation Catalyst and the First Rhodium(I) cis-Phosphine—cis-Ether Complex Characterized by Single-Crystal X-ray Diffraction Methods

AU - Allgeier, Alan M.

AU - Singewald, Elizabeth T.

AU - Mirkin, Chad A

AU - Stern, Charlotte L.

PY - 1994/8/1

Y1 - 1994/8/1

N2 - The synthesis, reactivity, and characterization of [Rh(η4-((η5-C5H4)OCH2CH2P(C6H5)2)2Fe)]BF4 (1) is reported. Compound 1 is the first example of a crystallographically characterized Rh(I) complex with a ligand array comprised exclusively of phosphine–ether moieties. The labile ethers in 1 render it susceptible to a variety of ligand substitution reactions and make it an olefin hydrogenation catalyst even in weakly coordinating solvents.

AB - The synthesis, reactivity, and characterization of [Rh(η4-((η5-C5H4)OCH2CH2P(C6H5)2)2Fe)]BF4 (1) is reported. Compound 1 is the first example of a crystallographically characterized Rh(I) complex with a ligand array comprised exclusively of phosphine–ether moieties. The labile ethers in 1 render it susceptible to a variety of ligand substitution reactions and make it an olefin hydrogenation catalyst even in weakly coordinating solvents.

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U2 - 10.1021/om00020a005

DO - 10.1021/om00020a005

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JO - Organometallics

JF - Organometallics

IS - 8

ER -

[Rh(η⁴-((η⁵-C₅H₄)OCH₂CH₂P(C₆H₅)₂)₂Fe)]BF₄: An Olefin Hydrogenation Catalyst and the First Rhodium(I) cis-Phosphine—cis-Ether Complex Characterized by Single-Crystal X-ray Diffraction Methods

Abstract

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