Rotationally inelastic scattering from surfaces CO(g) + LiF(OO1)

J. W. Hepburn; F. J. Northrup; G. L. Ogram; J. C. Polanyi; J. M. Willamson

doi:10.1016/0009-2614(82)80315-1

Rotationally inelastic scattering from surfaces CO(g) + LiF(OO1)

J. W. Hepburn^*, F. J. Northrup, G. L. Ogram, J. C. Polanyi, J. M. Willamson

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

99 Scopus citations

Abstract

The rotationally inelastic scattering of a supersonic, rotanonally cold (T_rot ^I = 4-30 k) CO molecular beam from a clean LiF(001) surface has been investigated by VUV laser-induced fluorescence. Rotational accommodation was incomplete for surface temperatures 350 < T_s < 900 K. The degree of accommodation decreased with T_s and was independent of collision energy.

Original language	English (US)
Pages (from-to)	127-130
Number of pages	4
Journal	Chemical Physics Letters
Volume	85
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(82)80315-1
State	Published - Jan 8 1982

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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abstract = "The rotationally inelastic scattering of a supersonic, rotanonally cold (Trot I = 4-30 k) CO molecular beam from a clean LiF(001) surface has been investigated by VUV laser-induced fluorescence. Rotational accommodation was incomplete for surface temperatures 350 < Ts < 900 K. The degree of accommodation decreased with Ts and was independent of collision energy.",

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AU - Northrup, F. J.

AU - Ogram, G. L.

AU - Polanyi, J. C.

AU - Willamson, J. M.

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