Rotaxane construction with a binaphthol-derived crown ether

Stuart J. Cantrill; Matthew C T Fyfe; Aaron M. Heiss; J. Fraser Stoddart; Andrew J P White; David J. Williams

doi:10.1039/a902096i

Rotaxane construction with a binaphthol-derived crown ether

Stuart J. Cantrill, Matthew C T Fyfe, Aaron M. Heiss, J. Fraser Stoddart^*, Andrew J P White, David J. Williams

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

31 Scopus citations

Abstract

Secondary dialkylammonium ions thread through the cavity of (RS)-benzo-2,2'-binaphtho[26]crown-8 to create [2]pseudorotaxanes, one of which was stoppered to produce a [2]rotaxane - incorporating the chiral binaphthyl unit - that was characterised by NMR spectroscopy, mass spectrometry and X-ray crystallography.

Original language	English (US)
Pages (from-to)	1251-1252
Number of pages	2
Journal	Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/a902096i
State	Published - Jul 7 1999

ASJC Scopus subject areas

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
Chemistry(all)
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

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title = "Rotaxane construction with a binaphthol-derived crown ether",

abstract = "Secondary dialkylammonium ions thread through the cavity of (RS)-benzo-2,2'-binaphtho[26]crown-8 to create [2]pseudorotaxanes, one of which was stoppered to produce a [2]rotaxane - incorporating the chiral binaphthyl unit - that was characterised by NMR spectroscopy, mass spectrometry and X-ray crystallography.",

author = "Cantrill, {Stuart J.} and Fyfe, {Matthew C T} and Heiss, {Aaron M.} and Stoddart, {J. Fraser} and White, {Andrew J P} and Williams, {David J.}",

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doi = "10.1039/a902096i",

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T1 - Rotaxane construction with a binaphthol-derived crown ether

AU - Cantrill, Stuart J.

AU - Fyfe, Matthew C T

AU - Heiss, Aaron M.

AU - Stoddart, J. Fraser

AU - White, Andrew J P

AU - Williams, David J.

PY - 1999/7/7

Y1 - 1999/7/7

N2 - Secondary dialkylammonium ions thread through the cavity of (RS)-benzo-2,2'-binaphtho[26]crown-8 to create [2]pseudorotaxanes, one of which was stoppered to produce a [2]rotaxane - incorporating the chiral binaphthyl unit - that was characterised by NMR spectroscopy, mass spectrometry and X-ray crystallography.

AB - Secondary dialkylammonium ions thread through the cavity of (RS)-benzo-2,2'-binaphtho[26]crown-8 to create [2]pseudorotaxanes, one of which was stoppered to produce a [2]rotaxane - incorporating the chiral binaphthyl unit - that was characterised by NMR spectroscopy, mass spectrometry and X-ray crystallography.

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DO - 10.1039/a902096i

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Rotaxane construction with a binaphthol-derived crown ether

Abstract

ASJC Scopus subject areas

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