[(Salcen)CrIII + Lewis base]-catalyzed synthesis of N-aryl-substituted oxazolidinones from epoxides and aryl isocyanates

Robert L. Paddock; Debashis Adhikari; Richard L. Lord; Mu Hyun Baik; Son Binh T. Nguyen

doi:10.1039/c4cc07421a

[(Salcen)Cr^III + Lewis base]-catalyzed synthesis of N-aryl-substituted oxazolidinones from epoxides and aryl isocyanates

Robert L. Paddock, Debashis Adhikari, Richard L. Lord, Mu Hyun Baik^*, Son Binh T. Nguyen

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

[(Salcen)Cr^III + Lewis base] was found to be a highly active and selective catalyst system in the [2+3] cycloaddition between epoxides and isocyanates to form 5-oxazolidinones. The reaction proceeds to high yield under mild reaction conditions and is applicable to a variety of terminal epoxides and aryl isocyanates.

Original language	English (US)
Pages (from-to)	15187-15190
Number of pages	4
Journal	Chemical Communications
Volume	50
Issue number	96
DOIs	https://doi.org/10.1039/c4cc07421a
State	Published - Nov 6 2014

Funding

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

Access to Document

10.1039/c4cc07421a

Cite this

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abstract = "[(Salcen)CrIII + Lewis base] was found to be a highly active and selective catalyst system in the [2+3] cycloaddition between epoxides and isocyanates to form 5-oxazolidinones. The reaction proceeds to high yield under mild reaction conditions and is applicable to a variety of terminal epoxides and aryl isocyanates.",

author = "Paddock, {Robert L.} and Debashis Adhikari and Lord, {Richard L.} and Baik, {Mu Hyun} and Nguyen, {Son Binh T.}",

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AU - Paddock, Robert L.

AU - Adhikari, Debashis

AU - Lord, Richard L.

AU - Baik, Mu Hyun

AU - Nguyen, Son Binh T.

PY - 2014/11/6

Y1 - 2014/11/6

N2 - [(Salcen)CrIII + Lewis base] was found to be a highly active and selective catalyst system in the [2+3] cycloaddition between epoxides and isocyanates to form 5-oxazolidinones. The reaction proceeds to high yield under mild reaction conditions and is applicable to a variety of terminal epoxides and aryl isocyanates.

AB - [(Salcen)CrIII + Lewis base] was found to be a highly active and selective catalyst system in the [2+3] cycloaddition between epoxides and isocyanates to form 5-oxazolidinones. The reaction proceeds to high yield under mild reaction conditions and is applicable to a variety of terminal epoxides and aryl isocyanates.

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