(Salen)chromium(III)/DMAP: An efficient catalyst system for the selective synthesis of 5-substituted oxazolidinones from carbon dioxide and aziridines

Aaron W. Miller; Son Binh T. Nguyen

doi:10.1021/ol049689t

(Salen)chromium(III)/DMAP: An efficient catalyst system for the selective synthesis of 5-substituted oxazolidinones from carbon dioxide and aziridines

Aaron W. Miller, Son Binh T. Nguyen^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

134 Scopus citations

Abstract

(Equation Presented) (Salen)chromium(III)/DMAP was found to be an active catalyst system for the coupling of CO₂ and aziridines. The oxazolidinone products were produced in high yield and selectivity from the opening of the aziridine at the most substituted N-C bond. This catalyst system worked well for a wide variety of monosubstituted N-aryl and N-alkyl aziridines as well as a 2,3-disubstituted N-alkyl aziridine.

Original language	English (US)
Pages (from-to)	2301-2304
Number of pages	4
Journal	Organic Letters
Volume	6
Issue number	14
DOIs	https://doi.org/10.1021/ol049689t
State	Published - Jul 8 2004

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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abstract = "(Equation Presented) (Salen)chromium(III)/DMAP was found to be an active catalyst system for the coupling of CO2 and aziridines. The oxazolidinone products were produced in high yield and selectivity from the opening of the aziridine at the most substituted N-C bond. This catalyst system worked well for a wide variety of monosubstituted N-aryl and N-alkyl aziridines as well as a 2,3-disubstituted N-alkyl aziridine.",

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AU - Miller, Aaron W.

AU - Nguyen, Son Binh T.

PY - 2004/7/8

Y1 - 2004/7/8

N2 - (Equation Presented) (Salen)chromium(III)/DMAP was found to be an active catalyst system for the coupling of CO2 and aziridines. The oxazolidinone products were produced in high yield and selectivity from the opening of the aziridine at the most substituted N-C bond. This catalyst system worked well for a wide variety of monosubstituted N-aryl and N-alkyl aziridines as well as a 2,3-disubstituted N-alkyl aziridine.

AB - (Equation Presented) (Salen)chromium(III)/DMAP was found to be an active catalyst system for the coupling of CO2 and aziridines. The oxazolidinone products were produced in high yield and selectivity from the opening of the aziridine at the most substituted N-C bond. This catalyst system worked well for a wide variety of monosubstituted N-aryl and N-alkyl aziridines as well as a 2,3-disubstituted N-alkyl aziridine.

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(Salen)chromium(III)/DMAP: An efficient catalyst system for the selective synthesis of 5-substituted oxazolidinones from carbon dioxide and aziridines

Abstract

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