TY - JOUR
T1 - Second-sphere co-ordination of neutral and cationic transition metal complexes by crown ethers
AU - Colquhoun, Howard M.
AU - Stoddart, J. Fraser
PY - 1981
Y1 - 1981
N2 - The [ammine(η5-cyclopentadienyl)dicarbonyliron(II)] cation and the neutral complex, amminepentacarbonyltungsten(0), form 1:1 adducts in solution with 18-crown-6 and dibenzo-18-crown-6 by virtue of hydrogen bonding between the ammine ligand in the transition metal complex and oxygen atoms of the crown ether; a crystalline adduct, [W(CO)5NH3.dibenzo- 18-crown-6], has been isolated as a benzene solvate.
AB - The [ammine(η5-cyclopentadienyl)dicarbonyliron(II)] cation and the neutral complex, amminepentacarbonyltungsten(0), form 1:1 adducts in solution with 18-crown-6 and dibenzo-18-crown-6 by virtue of hydrogen bonding between the ammine ligand in the transition metal complex and oxygen atoms of the crown ether; a crystalline adduct, [W(CO)5NH3.dibenzo- 18-crown-6], has been isolated as a benzene solvate.
UR - http://www.scopus.com/inward/record.url?scp=37049091502&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=37049091502&partnerID=8YFLogxK
U2 - 10.1039/c39810000612
DO - 10.1039/c39810000612
M3 - Article
AN - SCOPUS:37049091502
SN - 0022-4936
SP - 612
EP - 613
JO - Journal of the Chemical Society, Chemical Communications
JF - Journal of the Chemical Society, Chemical Communications
IS - 12
ER -