The [ammine(η5-cyclopentadienyl)dicarbonyliron(II)] cation and the neutral complex, amminepentacarbonyltungsten(0), form 1:1 adducts in solution with 18-crown-6 and dibenzo-18-crown-6 by virtue of hydrogen bonding between the ammine ligand in the transition metal complex and oxygen atoms of the crown ether; a crystalline adduct, [W(CO)5NH3.dibenzo- 18-crown-6], has been isolated as a benzene solvate.
|Original language||English (US)|
|Number of pages||2|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - 1981|
ASJC Scopus subject areas
- Molecular Medicine