Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor

David R. Alston; Alexandra M Z Slawin; J. Fraser Stoddart; David J. Williams; Ryszard Zarzycki

doi:10.1002/anie.198706921

Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor

David R. Alston, Alexandra M Z Slawin, J. Fraser Stoddart^*, David J. Williams, Ryszard Zarzycki

^*Corresponding author for this work

Chemistry

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18 Scopus citations

Abstract

Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH₃)₄][PF₆]₂ forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH₃ on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)

Original language	English (US)
Pages (from-to)	692-693
Number of pages	2
Journal	Angewandte Chemie International Edition in English
Volume	26
Issue number	7
DOIs	https://doi.org/10.1002/anie.198706921
State	Published - Jul 1987

ASJC Scopus subject areas

Catalysis
General Chemistry

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title = "Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor",

abstract = "Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH3)4][PF6]2 forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH3 on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)",

author = "Alston, {David R.} and Slawin, {Alexandra M Z} and Stoddart, {J. Fraser} and Williams, {David J.} and Ryszard Zarzycki",

year = "1987",

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AU - Alston, David R.

AU - Slawin, Alexandra M Z

AU - Stoddart, J. Fraser

AU - Williams, David J.

AU - Zarzycki, Ryszard

PY - 1987/7

Y1 - 1987/7

N2 - Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH3)4][PF6]2 forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH3 on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)

AB - Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH3)4][PF6]2 forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH3 on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)

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Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor

Abstract

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