Second Sphere Coordination of Tetraammineplatinum(II) by a Macropolycyclic Crown Ether Bisamide Receptor

David R. Alston, Alexandra M Z Slawin, J. Fraser Stoddart*, David J. Williams, Ryszard Zarzycki

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

17 Scopus citations

Abstract

Second sphere coordination of two receptor molecules to a metal complex has been observed for the macropolycycle 1. [Pt(NH3)4][PF6]2 forms discrete adducts with two molecules of 1; H‐bridges between carbonylO and etherO atoms on the one hand and NH3 on the other are crucial. Cisplatin does not form any adducts with 1. (Figure Presented.)

Original languageEnglish (US)
Pages (from-to)692-693
Number of pages2
JournalAngewandte Chemie International Edition in English
Volume26
Issue number7
DOIs
StatePublished - Jul 1987

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)

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