Seeded growth of single-crystal two-dimensional covalent organic frameworks

Austin M. Evans, Lucas R. Parent, Nathan C. Flanders, Ryan P. Bisbey, Edon Vitaku, Matthew S. Kirschner, Richard D. Schaller, Lin X. Chen, Nathan C. Gianneschi, William R. Dichtel*

*Corresponding author for this work

Research output: Contribution to journalArticle

141 Scopus citations

Abstract

Polymerization of monomers into periodic two-dimensional networks provides structurally precise, layered macromolecular sheets that exhibit desirable mechanical, optoelectronic, and molecular transport properties. Two-dimensional covalent organic frameworks (2D COFs) offer broad monomer scope but are generally isolated as powders comprising aggregated nanometer-scale crystallites. We found that 2D COF formation could be controlled using a two-step procedure in which monomers are added slowly to preformed nanoparticle seeds. The resulting 2D COFs are isolated as single-crystalline, micrometer-sized particles. Transient absorption spectroscopy of the dispersed COF nanoparticles revealed improvement in signal quality by two to three orders of magnitude relative to polycrystalline powder samples, and suggests exciton diffusion over longer length scales than those obtained through previous approaches. These findings should enable a broad exploration of synthetic 2D polymer structures and properties.

Original languageEnglish (US)
Pages (from-to)52-57
Number of pages6
JournalScience
Volume361
Issue number6397
DOIs
StatePublished - Jul 6 2018

ASJC Scopus subject areas

  • General

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