Selective Area Regrowth Produces Nonuniform Mg Doping Profiles in Nonplanar GaN p-n Junctions

Alexander S. Chang, Bingjun Li, Sizhen Wang, Mohsen Nami, Paul J.M. Smeets, Jung Han, Lincoln J. Lauhon*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

15 Scopus citations

Abstract

Nonplanar GaN p-n junctions formed by selective area regrowth were analyzed using pulsed laser atom probe tomography. Dilute Al marker layers were used to map the evolution of the p-GaN growth interface, enabling extraction of time-varying growth rates for nonpolar, semipolar, and polar surfaces from the trench edge to the center, respectively. The Mg dopant concentration is facet-dependent and varies inversely with the growth rate for the semipolar facets that grow rapidly away from the trench sidewalls. The negligible growth on the vertical sidewall of the trench coincides with an order of magnitude higher Mg concentration and substantial clustering of likely inactive dopants. A high Mg concentration is also observed near the regrowth interface of polar and semipolar planes, which we attribute to etching damage. We conclude that device fabrication processes employing selective area regrowth on nonplanar interfaces should consider both the spatial and temporal dependencies of growth rate that lead to nonuniform doping and explore growth conditions that could reduce variations in growth rate when nonuniform doping would adversely affect device performance.

Original languageEnglish (US)
Pages (from-to)704-710
Number of pages7
JournalACS Applied Electronic Materials
Volume3
Issue number2
DOIs
StatePublished - Feb 23 2021

Funding

This work is supported by the Advanced Research Projects Agency-Energy (ARPA-E), U.S. Department of Energy, under Award Number DE-AR0000871 as part of the PNDIODES program managed by Dr. Isik Kizilyalli. NUCAPT is a Research Core Facility of the Materials Research Science and Engineering Center (MRSEC) of Northwestern University, supported by the National Science Foundation’s MRSEC Program (grant number DMR-1121262). Additional instrumentation at NUCAPT is supported by the Initiative for Sustainability and Energy at Northwestern (ISEN). This work made use of the EPIC facility of Northwestern University’s NUANCE Center, which has received support from the Soft and Hybrid Nanotechnology Experimental (SHyNE) Resource (NSF ECCS-1542205); the MRSEC program (NSF DMR-1121262) at the Materials Research Center; the International Institute for Nanotechnology (IIN); the Keck Foundation; and the State of Illinois through the IIN.

Keywords

  • atom probe tomography
  • dopant profiling
  • gallium nitride
  • p-n junction
  • selective area doping
  • selective area regrowth

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Materials Chemistry
  • Electrochemistry

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