Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry

Research output: Contribution to journalArticlepeer-review

181 Scopus citations

Abstract

(Chemical Equation Presented) A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.

Original languageEnglish (US)
Pages (from-to)13613-13615
Number of pages3
JournalJournal of the American Chemical Society
Volume131
Issue number38
DOIs
StatePublished - 2009

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry

Fingerprint Dive into the research topics of 'Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry'. Together they form a unique fingerprint.

Cite this