(Chemical Equation Presented) A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.
|Original language||English (US)|
|Number of pages||3|
|Journal||Journal of the American Chemical Society|
|State||Published - 2009|
ASJC Scopus subject areas
- Colloid and Surface Chemistry
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CCDC 780884: Experimental Crystal Structure Determination
Gadzikwa, T. (Creator), Farha, O. K. (Creator), Malliakas, C. D. (Creator), Kanatzidis, M. (Creator), Hupp, J. T. (Creator) & Nguyen, S. (Creator), Cambridge Crystallographic Data Centre, 2010
DOI: 10.5517/ccv6ktd, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.5517/ccv6ktd&sid=DataCite