Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry

Tendai Gadzikwa; Omar K. Farha; Christos D. Malliakas; Mercouri G. Kanatzidis; Joseph T. Hupp; Son Binh T. Nguyen

doi:10.1021/ja904189d

Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry

Tendai Gadzikwa, Omar K. Farha, Christos D. Malliakas, Mercouri G. Kanatzidis, Joseph T. Hupp, Son Binh T. Nguyen

Chemistry

Research output: Contribution to journal › Article › peer-review

203 Scopus citations

Abstract

(Chemical Equation Presented) A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.

Original language	English (US)
Pages (from-to)	13613-13615
Number of pages	3
Journal	Journal of the American Chemical Society
Volume	131
Issue number	38
DOIs	https://doi.org/10.1021/ja904189d
State	Published - 2009

Funding

ASJC Scopus subject areas

General Chemistry
Biochemistry
Catalysis
Colloid and Surface Chemistry

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10.1021/ja904189d

Cite this

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abstract = "(Chemical Equation Presented) A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using {"}click{"} chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were {"}clicked{"} onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.",

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year = "2009",

doi = "10.1021/ja904189d",

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T1 - Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry

AU - Gadzikwa, Tendai

AU - Farha, Omar K.

AU - Malliakas, Christos D.

AU - Kanatzidis, Mercouri G.

AU - Hupp, Joseph T.

AU - Nguyen, Son Binh T.

PY - 2009

Y1 - 2009

N2 - (Chemical Equation Presented) A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.

AB - (Chemical Equation Presented) A noncatenated, Zn-based metal-organic framework (MOF) material bearing silyl-protected acetylenes was constructed and postsynthetically modified using "click" chemistry. Using a solvent-based, selective deprotection strategy, two different organic azides were "clicked" onto the MOF crystals, resulting in a porous material whose internal and external surfaces are differently functionalized.

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JF - Journal of the American Chemical Society

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ER -

Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry

Abstract

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ASJC Scopus subject areas

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CCDC 780884: Experimental Crystal Structure Determination

Cite this

Selective bifunctional modification of a non-catenated metal-organic framework material via "click" chemistry

Abstract

Funding

ASJC Scopus subject areas

Access to Document

Other files and links

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Datasets

CCDC 780884: Experimental Crystal Structure Determination

Cite this