Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks

Marianne B. Lalonde; Joseph E. Mondloch; Pravas Deria; Amy A. Sarjeant; Salih S. Al-Juaid; Osman I. Osman; Omar K. Farha; Joseph T. Hupp

doi:10.1021/acs.inorgchem.5b01231

Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks

Marianne B. Lalonde, Joseph E. Mondloch, Pravas Deria, Amy A. Sarjeant, Salih S. Al-Juaid, Osman I. Osman, Omar K. Farha^*, Joseph T. Hupp

^*Corresponding author for this work

Chemistry

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50 Scopus citations

Abstract

Solvent-assisted linker exchange (SALE) has recently emerged as an attractive strategy for the synthesis of metal-organic frameworks (MOFs) that are unobtainable via traditional synthetic pathways. Herein we present the first example of selective SALE in which only the benzimiadazolate-containing linkers in a series of mixed-linker zeolitic imidazolate frameworks (ZIF-69, -78, and -76) are replaced. The resultant materials (SALEM-10, SALEM-10b, and SALEM-11, respectively) are isostructural to the parent framework and in each case contain trifluoromethyl moieties. We therefore evaluated each of these materials for their hydrophobicity in condensed and gas phases. We expect that selective SALE will significantly facilitate the design of improved, and potentially complex, MOF materials with new and unusual properties.

Original language	English (US)
Pages (from-to)	7142-7144
Number of pages	3
Journal	Inorganic chemistry
Volume	54
Issue number	15
DOIs	https://doi.org/10.1021/acs.inorgchem.5b01231
State	Published - Aug 3 2015

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks",

abstract = "Solvent-assisted linker exchange (SALE) has recently emerged as an attractive strategy for the synthesis of metal-organic frameworks (MOFs) that are unobtainable via traditional synthetic pathways. Herein we present the first example of selective SALE in which only the benzimiadazolate-containing linkers in a series of mixed-linker zeolitic imidazolate frameworks (ZIF-69, -78, and -76) are replaced. The resultant materials (SALEM-10, SALEM-10b, and SALEM-11, respectively) are isostructural to the parent framework and in each case contain trifluoromethyl moieties. We therefore evaluated each of these materials for their hydrophobicity in condensed and gas phases. We expect that selective SALE will significantly facilitate the design of improved, and potentially complex, MOF materials with new and unusual properties.",

author = "Lalonde, {Marianne B.} and Mondloch, {Joseph E.} and Pravas Deria and Sarjeant, {Amy A.} and Al-Juaid, {Salih S.} and Osman, {Osman I.} and Farha, {Omar K.} and Hupp, {Joseph T.}",

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doi = "10.1021/acs.inorgchem.5b01231",

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T1 - Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks

AU - Lalonde, Marianne B.

AU - Mondloch, Joseph E.

AU - Deria, Pravas

AU - Sarjeant, Amy A.

AU - Al-Juaid, Salih S.

AU - Osman, Osman I.

AU - Farha, Omar K.

AU - Hupp, Joseph T.

PY - 2015/8/3

Y1 - 2015/8/3

N2 - Solvent-assisted linker exchange (SALE) has recently emerged as an attractive strategy for the synthesis of metal-organic frameworks (MOFs) that are unobtainable via traditional synthetic pathways. Herein we present the first example of selective SALE in which only the benzimiadazolate-containing linkers in a series of mixed-linker zeolitic imidazolate frameworks (ZIF-69, -78, and -76) are replaced. The resultant materials (SALEM-10, SALEM-10b, and SALEM-11, respectively) are isostructural to the parent framework and in each case contain trifluoromethyl moieties. We therefore evaluated each of these materials for their hydrophobicity in condensed and gas phases. We expect that selective SALE will significantly facilitate the design of improved, and potentially complex, MOF materials with new and unusual properties.

AB - Solvent-assisted linker exchange (SALE) has recently emerged as an attractive strategy for the synthesis of metal-organic frameworks (MOFs) that are unobtainable via traditional synthetic pathways. Herein we present the first example of selective SALE in which only the benzimiadazolate-containing linkers in a series of mixed-linker zeolitic imidazolate frameworks (ZIF-69, -78, and -76) are replaced. The resultant materials (SALEM-10, SALEM-10b, and SALEM-11, respectively) are isostructural to the parent framework and in each case contain trifluoromethyl moieties. We therefore evaluated each of these materials for their hydrophobicity in condensed and gas phases. We expect that selective SALE will significantly facilitate the design of improved, and potentially complex, MOF materials with new and unusual properties.

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JO - Inorganic chemistry

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Selective Solvent-Assisted Linker Exchange (SALE) in a Series of Zeolitic Imidazolate Frameworks

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