Self-assembly of an amphiphilic [2]rotaxane incorporating a tetrathiafulvalene unit

Jan Oskar Jeppesen; Julie Perkins; Jan Becher; J. Fraser Stoddart

doi:10.1021/ol006387s

Self-assembly of an amphiphilic [2]rotaxane incorporating a tetrathiafulvalene unit

Jan Oskar Jeppesen, Julie Perkins, Jan Becher, J. Fraser Stoddart^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

(matrix presented) The template-directed synthesis of a [2]rotaxane, in which a π-electron deficient ring component - cyclobis(paraquat-p-phenylene) - is assembled around a π-electron rich asymmetric monopyrrolotetrathiafulvalene unit on the rod section of an amphiphilic dumbbell component that is terminated by a hydrophilic dendritic stopper at one end and a hydrophobic tetraarylmethane stopper at the other end, is reported.

Original language	English (US)
Pages (from-to)	3547-3550
Number of pages	4
Journal	Organic Letters
Volume	2
Issue number	23
DOIs	https://doi.org/10.1021/ol006387s
State	Published - Nov 16 2000

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

Access to Document

10.1021/ol006387s

Cite this

@article{2d245537acb147a98ef860c48e0c7edc,

title = "Self-assembly of an amphiphilic [2]rotaxane incorporating a tetrathiafulvalene unit",

abstract = "(matrix presented) The template-directed synthesis of a [2]rotaxane, in which a π-electron deficient ring component - cyclobis(paraquat-p-phenylene) - is assembled around a π-electron rich asymmetric monopyrrolotetrathiafulvalene unit on the rod section of an amphiphilic dumbbell component that is terminated by a hydrophilic dendritic stopper at one end and a hydrophobic tetraarylmethane stopper at the other end, is reported.",

author = "Jeppesen, {Jan Oskar} and Julie Perkins and Jan Becher and Stoddart, {J. Fraser}",

year = "2000",

month = nov,

day = "16",

doi = "10.1021/ol006387s",

language = "English (US)",

volume = "2",

pages = "3547--3550",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "23",

}

TY - JOUR

T1 - Self-assembly of an amphiphilic [2]rotaxane incorporating a tetrathiafulvalene unit

AU - Jeppesen, Jan Oskar

AU - Perkins, Julie

AU - Becher, Jan

AU - Stoddart, J. Fraser

PY - 2000/11/16

Y1 - 2000/11/16

N2 - (matrix presented) The template-directed synthesis of a [2]rotaxane, in which a π-electron deficient ring component - cyclobis(paraquat-p-phenylene) - is assembled around a π-electron rich asymmetric monopyrrolotetrathiafulvalene unit on the rod section of an amphiphilic dumbbell component that is terminated by a hydrophilic dendritic stopper at one end and a hydrophobic tetraarylmethane stopper at the other end, is reported.

AB - (matrix presented) The template-directed synthesis of a [2]rotaxane, in which a π-electron deficient ring component - cyclobis(paraquat-p-phenylene) - is assembled around a π-electron rich asymmetric monopyrrolotetrathiafulvalene unit on the rod section of an amphiphilic dumbbell component that is terminated by a hydrophilic dendritic stopper at one end and a hydrophobic tetraarylmethane stopper at the other end, is reported.

UR - http://www.scopus.com/inward/record.url?scp=0001010648&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=0001010648&partnerID=8YFLogxK

U2 - 10.1021/ol006387s

DO - 10.1021/ol006387s

M3 - Article

C2 - 11073641

AN - SCOPUS:0001010648

SN - 1523-7060

VL - 2

SP - 3547

EP - 3550

JO - Organic Letters

JF - Organic Letters

IS - 23

ER -

Self-assembly of an amphiphilic [2]rotaxane incorporating a tetrathiafulvalene unit

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this