Self-assembly of polyoxoselenitopalladate nanostars [Pd153-SeO3)103-O) 10Na]9- and their supramolecular pairing in the solid state

Massimiliano Delferro*, Claudia Graiff, Lisa Elviri, Giovanni Predieri

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

37 Scopus citations

Abstract

An anionic Pd15-oxo-cluster [Pd153- SeO3)103-O)10Na]9- has been synthesized. It is the result of an unprecedented self-assembly of Pd2+ and Na+ cations, SeO32- and oxo anions. It has been found for the first time, that selenito groups can give rise to supramolecular interactions in the solid state with palladium atoms, through the selenium electron lone pairs.

Original languageEnglish (US)
Pages (from-to)4479-4481
Number of pages3
JournalDalton Transactions
Volume39
Issue number19
DOIs
StatePublished - May 11 2010

ASJC Scopus subject areas

  • Inorganic Chemistry

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