Abstract
An anionic Pd15-oxo-cluster [Pd15(μ3- SeO3)10(μ3-O)10Na]9- has been synthesized. It is the result of an unprecedented self-assembly of Pd2+ and Na+ cations, SeO32- and oxo anions. It has been found for the first time, that selenito groups can give rise to supramolecular interactions in the solid state with palladium atoms, through the selenium electron lone pairs.
Original language | English (US) |
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Pages (from-to) | 4479-4481 |
Number of pages | 3 |
Journal | Dalton Transactions |
Volume | 39 |
Issue number | 19 |
DOIs | |
State | Published - May 11 2010 |
ASJC Scopus subject areas
- Inorganic Chemistry
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Dive into the research topics of 'Self-assembly of polyoxoselenitopalladate nanostars [Pd15(μ 3-SeO3)10(μ3-O) 10Na]9- and their supramolecular pairing in the solid state'. Together they form a unique fingerprint.Datasets
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CSD 761436: Experimental Crystal Structure Determination
Delferro, M. (Creator), Graiff, C. (Creator), Elviri, L. (Creator) & Predieri, G. (Creator), FIZ Karlsruhe – Leibniz Institute for Information Infrastructure, 2010
DOI: 10.25505/fiz.icsd.cctkbg4, http://www.ccdc.cam.ac.uk/services/structure_request?id=doi:10.25505/fiz.icsd.cctkbg4&sid=DataCite
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