Self-replication vs. reactive binary complexes - Manipulating recognition-mediated cycloadditions by simple structural modifications

Russell J. Pearson; Eleftherios Kassianidis; Alexandra M.Z. Slawin; Douglas Philp

doi:10.1039/b406862a

Self-replication vs. reactive binary complexes - Manipulating recognition-mediated cycloadditions by simple structural modifications

Russell J. Pearson, Eleftherios Kassianidis, Alexandra M.Z. Slawin, Douglas Philp^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

35 Scopus citations

Abstract

The rate of reaction and the selectivity of a Diels - Alder cycloaddition between a furan and a maleimide can be enhanced by the introduction of complementary recognition sites on the reactant species. Subtle manipulation of other structural elements allows the generation of the observed rate enhancements and selectivities through either self-replication or formation of a pre-reactivc binary complex.

Original language	English (US)
Pages (from-to)	3434-3441
Number of pages	8
Journal	Organic and Biomolecular Chemistry
Volume	2
Issue number	23
DOIs	https://doi.org/10.1039/b406862a
State	Published - Dec 7 2004

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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Self-replication vs. reactive binary complexes - Manipulating recognition-mediated cycloadditions by simple structural modifications

Abstract

ASJC Scopus subject areas

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