Sequential electrochemical oxidation of alternating benzene-furan oligomers

Cheng Lan Lin; Yi Lin Wu; Chang Li Chen; Chih Ming Chou; Tien Yau Luh

doi:10.1021/jo070999+

Sequential electrochemical oxidation of alternating benzene-furan oligomers

Cheng Lan Lin, Yi Lin Wu, Chang Li Chen, Chih Ming Chou, Tien Yau Luh^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

(Graph Presented) Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.

Original language	English (US)
Pages (from-to)	8531-8534
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	72
Issue number	22
DOIs	https://doi.org/10.1021/jo070999+
State	Published - Oct 26 2007

ASJC Scopus subject areas

Organic Chemistry

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title = "Sequential electrochemical oxidation of alternating benzene-furan oligomers",

abstract = "(Graph Presented) Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.",

author = "Lin, {Cheng Lan} and Wu, {Yi Lin} and Chen, {Chang Li} and Chou, {Chih Ming} and Luh, {Tien Yau}",

year = "2007",

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day = "26",

doi = "10.1021/jo070999+",

language = "English (US)",

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journal = "Journal of Organic Chemistry",

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T1 - Sequential electrochemical oxidation of alternating benzene-furan oligomers

AU - Lin, Cheng Lan

AU - Wu, Yi Lin

AU - Chen, Chang Li

AU - Chou, Chih Ming

AU - Luh, Tien Yau

PY - 2007/10/26

Y1 - 2007/10/26

N2 - (Graph Presented) Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.

AB - (Graph Presented) Electrochemical oxidation of pentaaryl 2 containing two furan moieties occurs sequentially to give diketone 8 after two-electron transfer. Further oxidation with another two-electron transfer gives the corresponding tetraketone 9. Radical cation intermediate is detected by absorption spectroscopy. The radical intermediates of different regiochemistry have been shown to exhibit different oxidation potentials as revealed by the differential pulse voltammetry.

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Sequential electrochemical oxidation of alternating benzene-furan oligomers

Abstract

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