Serendipitous desymmetrisation during porphyrazine synthesis: An X-ray crystallographic study of 2,3,7,8,12,13,17,18-octakis(dimethylamino)-2- secoporphyrazine-2,3-dione

Neelakandha S. Mani, L. Scott Beall, Andrew J.P. White, David J. Williams, Anthony G.M. Barrett*, Brian M Hoffman

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

34 Scopus citations

Abstract

Linstead macrocyclisation of 2,3-bis(dimethylamino)2(Z)-butenedinitrile gives [2,3,7,8,12,13,17,18-octakis(dimethylamino)porphyrazato]magnesium(II) and the title seco-porphyrazine, the structure of which is established by an X-ray crystallographic study.

Original languageEnglish (US)
Pages (from-to)1943-1944
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number17
DOIs
StatePublished - Dec 1 1994

ASJC Scopus subject areas

  • Molecular Medicine

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