Serendipitous synthesis of trimetallic porphyrazine triads

Tomasz Goslinski, Chang Zhong, Matthew J. Fuchter, Andrew J.P. White, Anthony G.M. Barrett*, Brian M. Hoffman

*Corresponding author for this work

Research output: Contribution to journalArticle

2 Scopus citations

Abstract

We report the synthesis and characterization of structurally unusual porphyrazine triads with three macrocycles bound to a central pyrazine core. These trimacrocyclic complexes were accidentally discovered during studies on the peripheral metallation of porphyrazinediamines. The crystal structure of the tri-zinc porphyrazine triad is described and the spectroscopic properties including electronic absorption spectra of this complex and the corresponding magnesium, free-base, and copper derivatives are reported.

Original languageEnglish (US)
Pages (from-to)5178-5181
Number of pages4
JournalTetrahedron Letters
Volume50
Issue number37
DOIs
StatePublished - Sep 16 2009

Keywords

  • Macrocycle
  • Metal complex
  • Peripheral metallation
  • Porphyrazine
  • Porphyrazinediamine

ASJC Scopus subject areas

  • Biochemistry
  • Drug Discovery
  • Organic Chemistry

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