Seven-Layered 2D Hybrid Lead Iodide Perovskites

Lingling Mao; Rhys M. Kennard; Boubacar Traore; Weijun Ke; Claudine Katan; Jacky Even; Michael L. Chabinyc; Constantinos C. Stoumpos; Mercouri G. Kanatzidis

doi:10.1016/j.chempr.2019.07.024

Seven-Layered 2D Hybrid Lead Iodide Perovskites

Lingling Mao, Rhys M. Kennard, Boubacar Traore, Weijun Ke, Claudine Katan, Jacky Even, Michael L. Chabinyc, Constantinos C. Stoumpos^*, Mercouri G. Kanatzidis

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

52 Scopus citations

Abstract

Seven-layered 2D lead iodide perovskites are the highest layer thickness halide perovskites crystallographically characterized to date. Comparing the structural and optical properties between the Ruddlesden-Popper (RP) phases and the Dion-Jacobson (DJ) phases is now possible and offers new insights in our deeper understanding of these materials and how to best implement them in optoelectronic applications.

Original language	English (US)
Pages (from-to)	2593-2604
Number of pages	12
Journal	Chem
Volume	5
Issue number	10
DOIs	https://doi.org/10.1016/j.chempr.2019.07.024
State	Published - Oct 10 2019

Keywords

2D semiconductors
SDG7: Affordable and clean energy
organic-inorganic hybrids
photoconductivity
solar cells

ASJC Scopus subject areas

Chemistry(all)
Biochemistry
Environmental Chemistry
Chemical Engineering(all)
Biochemistry, medical
Materials Chemistry

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10.1016/j.chempr.2019.07.024

Cite this

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title = "Seven-Layered 2D Hybrid Lead Iodide Perovskites",

abstract = "Seven-layered 2D lead iodide perovskites are the highest layer thickness halide perovskites crystallographically characterized to date. Comparing the structural and optical properties between the Ruddlesden-Popper (RP) phases and the Dion-Jacobson (DJ) phases is now possible and offers new insights in our deeper understanding of these materials and how to best implement them in optoelectronic applications.",

keywords = "2D semiconductors, SDG7: Affordable and clean energy, organic-inorganic hybrids, photoconductivity, solar cells",

author = "Lingling Mao and Kennard, {Rhys M.} and Boubacar Traore and Weijun Ke and Claudine Katan and Jacky Even and Chabinyc, {Michael L.} and Stoumpos, {Constantinos C.} and Kanatzidis, {Mercouri G.}",

note = "Funding Information: This work was mainly supported by the Department of Energy, Office of Science, Basic Energy Sciences, under grant SC0012541 (synthesis, structure characterization, and TEM analysis). DFT calculations were performed at the Institut des Sciences Chimiques de Rennes, which received funding from the Agence Nationale pour la Recherche (TRANSHYPERO project), and the work was granted access to the HPC resources of TGCC/CINES/IDRIS under the allocation 2017-A0010907682 made by GENCI. The stability studies (C.C.S.) were supported by ONR grant N00014-17-1-2231. M.G.K. L.M. and C.C.S. conceived the idea. L.M. conducted and designed the experiments and wrote the paper. R.M.K. conducted the TEM experiments. B.T. C.K. and J.E. conducted the DFT calculations. All authors discussed the results and wrote the paper. The authors declare no competing interests. Funding Information: This work was mainly supported by the Department of Energy, Office of Science, Basic Energy Sciences , under grant SC0012541 (synthesis, structure characterization, and TEM analysis). DFT calculations were performed at the Institut des Sciences Chimiques de Rennes, which received funding from the Agence Nationale pour la Recherche (TRANSHYPERO project), and the work was granted access to the HPC resources of TGCC/CINES/IDRIS under the allocation 2017- A0010907682 made by GENCI. The stability studies (C.C.S.) were supported by ONR grant N00014-17-1-2231 . Publisher Copyright: {\textcopyright} 2019 Elsevier Inc.",

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doi = "10.1016/j.chempr.2019.07.024",

language = "English (US)",

volume = "5",

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AU - Mao, Lingling

AU - Kennard, Rhys M.

AU - Traore, Boubacar

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AU - Katan, Claudine

AU - Even, Jacky

AU - Chabinyc, Michael L.

AU - Stoumpos, Constantinos C.

AU - Kanatzidis, Mercouri G.

N1 - Funding Information: This work was mainly supported by the Department of Energy, Office of Science, Basic Energy Sciences, under grant SC0012541 (synthesis, structure characterization, and TEM analysis). DFT calculations were performed at the Institut des Sciences Chimiques de Rennes, which received funding from the Agence Nationale pour la Recherche (TRANSHYPERO project), and the work was granted access to the HPC resources of TGCC/CINES/IDRIS under the allocation 2017-A0010907682 made by GENCI. The stability studies (C.C.S.) were supported by ONR grant N00014-17-1-2231. M.G.K. L.M. and C.C.S. conceived the idea. L.M. conducted and designed the experiments and wrote the paper. R.M.K. conducted the TEM experiments. B.T. C.K. and J.E. conducted the DFT calculations. All authors discussed the results and wrote the paper. The authors declare no competing interests. Funding Information: This work was mainly supported by the Department of Energy, Office of Science, Basic Energy Sciences , under grant SC0012541 (synthesis, structure characterization, and TEM analysis). DFT calculations were performed at the Institut des Sciences Chimiques de Rennes, which received funding from the Agence Nationale pour la Recherche (TRANSHYPERO project), and the work was granted access to the HPC resources of TGCC/CINES/IDRIS under the allocation 2017- A0010907682 made by GENCI. The stability studies (C.C.S.) were supported by ONR grant N00014-17-1-2231 . Publisher Copyright: © 2019 Elsevier Inc.

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N2 - Seven-layered 2D lead iodide perovskites are the highest layer thickness halide perovskites crystallographically characterized to date. Comparing the structural and optical properties between the Ruddlesden-Popper (RP) phases and the Dion-Jacobson (DJ) phases is now possible and offers new insights in our deeper understanding of these materials and how to best implement them in optoelectronic applications.

AB - Seven-layered 2D lead iodide perovskites are the highest layer thickness halide perovskites crystallographically characterized to date. Comparing the structural and optical properties between the Ruddlesden-Popper (RP) phases and the Dion-Jacobson (DJ) phases is now possible and offers new insights in our deeper understanding of these materials and how to best implement them in optoelectronic applications.

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KW - SDG7: Affordable and clean energy

KW - organic-inorganic hybrids

KW - photoconductivity

KW - solar cells

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JO - Chem

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ER -

Seven-Layered 2D Hybrid Lead Iodide Perovskites

Abstract

Keywords

ASJC Scopus subject areas

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CCDC 1919628: Experimental Crystal Structure Determination

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Seven-Layered 2D Hybrid Lead Iodide Perovskites

Abstract

Keywords

ASJC Scopus subject areas

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Datasets

CCDC 1919628: Experimental Crystal Structure Determination

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