Short-range order in defective half-Heusler thermoelectric crystals

Kaiyang Xia, Pengfei Nan, Shihua Tan, Yumei Wang, Binghui Ge, Wenqing Zhang*, Shashwat Anand, Xinbing Zhao, Gerald Jeffrey Snyder, Tiejun Zhu

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

16 Scopus citations

Abstract

Crystalline solids are characterized by periodic structures, resulting in a diverse assortment of crystal structures that exhibit a wide variety of properties. Here we report short-range order, which results in characteristic diffuse bands in electron diffraction patterns, in a series of defective 19-electron half-Heusler compounds for the first time. The co-existence of the vacancy-related short-range order and the crystalline long-range periodic structure makes these defective half-Heusler compounds promising thermoelectric materials with low thermal conductivity and high electrical conductivity simultaneously. This new finding provides important insights into the intrinsic nature of defective HH compounds, and also proposes a possible strategy for tuning the degree of ordering to offer great potential for further improvement of thermoelectrics.

Original languageEnglish (US)
Pages (from-to)1568-1574
Number of pages7
JournalEnergy and Environmental Science
Volume12
Issue number5
DOIs
StatePublished - May 1 2019

ASJC Scopus subject areas

  • Environmental Chemistry
  • Renewable Energy, Sustainability and the Environment
  • Nuclear Energy and Engineering
  • Pollution

Fingerprint Dive into the research topics of 'Short-range order in defective half-Heusler thermoelectric crystals'. Together they form a unique fingerprint.

Cite this