Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts [3]

Haruyuki Makio; Kwangmo Koo; Tobin Jay Marks

doi:10.1021/ma010082r

Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts [3]

Haruyuki Makio, Kwangmo Koo, Tobin Jay Marks^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Letter › peer-review

3 Scopus citations

Abstract

Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts was reported. Polymerizations were carried out in toluene slurries under rigorously anhydrous/anaerobic high-vacuum line conditions. Catalyst SiO₂/MAO/1 exhibited reasonable activity in the absence of silane. It was found that the molecular weight of the product polymer was significantly higher than that produced by comparable homogeneous systems and the PDI was slightly larger than 2.0.

Original language	English (US)
Pages (from-to)	4676-4679
Number of pages	4
Journal	Macromolecules
Volume	34
Issue number	14
DOIs	https://doi.org/10.1021/ma010082r
State	Published - Jul 3 2001

ASJC Scopus subject areas

Organic Chemistry
Polymers and Plastics
Inorganic Chemistry
Materials Chemistry

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10.1021/ma010082r

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title = "Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts [3]",

abstract = "Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts was reported. Polymerizations were carried out in toluene slurries under rigorously anhydrous/anaerobic high-vacuum line conditions. Catalyst SiO2/MAO/1 exhibited reasonable activity in the absence of silane. It was found that the molecular weight of the product polymer was significantly higher than that produced by comparable homogeneous systems and the PDI was slightly larger than 2.0.",

author = "Haruyuki Makio and Kwangmo Koo and Marks, {Tobin Jay}",

year = "2001",

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T1 - Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts [3]

AU - Makio, Haruyuki

AU - Koo, Kwangmo

AU - Marks, Tobin Jay

PY - 2001/7/3

Y1 - 2001/7/3

N2 - Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts was reported. Polymerizations were carried out in toluene slurries under rigorously anhydrous/anaerobic high-vacuum line conditions. Catalyst SiO2/MAO/1 exhibited reasonable activity in the absence of silane. It was found that the molecular weight of the product polymer was significantly higher than that produced by comparable homogeneous systems and the PDI was slightly larger than 2.0.

AB - Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts was reported. Polymerizations were carried out in toluene slurries under rigorously anhydrous/anaerobic high-vacuum line conditions. Catalyst SiO2/MAO/1 exhibited reasonable activity in the absence of silane. It was found that the molecular weight of the product polymer was significantly higher than that produced by comparable homogeneous systems and the PDI was slightly larger than 2.0.

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DO - 10.1021/ma010082r

M3 - Letter

AN - SCOPUS:0035800306

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JO - Macromolecules

JF - Macromolecules

IS - 14

ER -

Silanolytic chain transfer in olefin polymerization with supported single-site Ziegler-Natta catalysts [3]

Abstract

ASJC Scopus subject areas

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