Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111

Yang Peng; Gadipelli Srinivas; Christopher E. Wilmer; Ibrahim Eryazici; Randall Q. Snurr; Omar K. Farha; Taner Yildirim

doi:10.1039/c3cc40819a

Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111

Yang Peng, Gadipelli Srinivas, Christopher E. Wilmer, Ibrahim Eryazici, Randall Q. Snurr, Omar K. Farha, Taner Yildirim^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

126 Scopus citations

Abstract

We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g⁻¹ and 284 cc(STP) per cc at 65 bar. Adsorption of CO₂ and H₂ is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.

Original language	English (US)
Pages (from-to)	2992-2994
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	29
DOIs	https://doi.org/10.1039/c3cc40819a
State	Published - Mar 14 2013

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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title = "Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111",

abstract = "We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g−1 and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.",

author = "Yang Peng and Gadipelli Srinivas and Wilmer, {Christopher E.} and Ibrahim Eryazici and Snurr, {Randall Q.} and Farha, {Omar K.} and Taner Yildirim",

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AU - Peng, Yang

AU - Srinivas, Gadipelli

AU - Wilmer, Christopher E.

AU - Eryazici, Ibrahim

AU - Snurr, Randall Q.

AU - Farha, Omar K.

AU - Yildirim, Taner

PY - 2013/3/14

Y1 - 2013/3/14

N2 - We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g−1 and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.

AB - We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g−1 and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.

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Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111

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