Simultaneously high gravimetric and volumetric methane uptake characteristics of the metal-organic framework NU-111

Yang Peng, Gadipelli Srinivas, Christopher E. Wilmer, Ibrahim Eryazici, Randall Q. Snurr, Omar K. Farha, Taner Yildirim*

*Corresponding author for this work

Research output: Contribution to journalArticle

98 Scopus citations

Abstract

We show that the MOF NU-111 exhibits equally high volumetric and gravimetric methane uptake values, both within ≈75% of the DOE targets at 300 K. Upon reducing the temperature to 270 K, the uptake increases to 0.5 g g−1 and 284 cc(STP) per cc at 65 bar. Adsorption of CO2 and H2 is also reported. Simulated isotherms are in excellent agreement with those obtained from experiments.

Original languageEnglish (US)
Pages (from-to)2992-2994
Number of pages3
JournalChemical Communications
Volume49
Issue number29
DOIs
StatePublished - Mar 14 2013

ASJC Scopus subject areas

  • Catalysis
  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Chemistry(all)
  • Surfaces, Coatings and Films
  • Metals and Alloys
  • Materials Chemistry

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