Simultaneously increasing cryogenic strength, ductility and impact resistance of epoxy resins modified by n-butyl glycidyl ether

Zhen Kun Chen, Guo Yang, Jiao Ping Yang, Shao Yun Fu*, Lin Ye, Yonggang Huang

*Corresponding author for this work

Research output: Contribution to journalArticle

90 Citations (Scopus)

Abstract

Epoxy resins are increasingly used in cryogenic engineering areas due to rapid developments of spacecraft and superconducting cable technologies as well as large cryogenic engineering projects (e.g., International Thermonuclear Experimental Reactor). Cryogenic mechanical properties are important parameters for epoxy resins to be employed in such areas. In this paper, a traditional reactive aliphatic diluent, namely n-butyl glycidyl ether (BGE, JX-013) with a low viscosity, was used to modify diethyl toluene diamine (DETD)-cured diglycidyl ether of bisphenol-F (DGEBF) epoxy system for enhancing cryogenic mechanical properties at liquid nitrogen temperature (77 K). The results showed that the cryogenic strength, ductility and impact resistance (impact strength) have been simultaneously enhanced by the addition of BGE with appropriate contents. Moreover, the comparison of the mechanical properties between 77 K and room temperature (RT) indicated that at the same composition, the tensile strength and Young's modulus at 77 K were higher than those at RT but the failure strain and impact resistance showed the opposite results. Finally, differential scanning calorimetry (DSC) exhibited that the glass transition temperatures (Tg) of the epoxy resins decreased with increasing the BGE content.

Original languageEnglish (US)
Pages (from-to)1316-1323
Number of pages8
JournalPolymer
Volume50
Issue number5
DOIs
StatePublished - Feb 23 2009

Fingerprint

Epoxy Resins
Impact resistance
Epoxy resins
Cryogenics
Ductility
Ethers
Mechanical properties
Superconducting cables
Experimental reactors
Diamines
Toluene
Impact strength
Liquid nitrogen
Temperature
Spacecraft
Differential scanning calorimetry
Tensile strength
Elastic moduli
n-butyl glycidyl ether
Viscosity

Keywords

  • Epoxy resin
  • Mechanical properties
  • n-Butyl glycidyl ether

ASJC Scopus subject areas

  • Organic Chemistry
  • Polymers and Plastics
  • Materials Chemistry

Cite this

Chen, Zhen Kun ; Yang, Guo ; Yang, Jiao Ping ; Fu, Shao Yun ; Ye, Lin ; Huang, Yonggang. / Simultaneously increasing cryogenic strength, ductility and impact resistance of epoxy resins modified by n-butyl glycidyl ether. In: Polymer. 2009 ; Vol. 50, No. 5. pp. 1316-1323.
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abstract = "Epoxy resins are increasingly used in cryogenic engineering areas due to rapid developments of spacecraft and superconducting cable technologies as well as large cryogenic engineering projects (e.g., International Thermonuclear Experimental Reactor). Cryogenic mechanical properties are important parameters for epoxy resins to be employed in such areas. In this paper, a traditional reactive aliphatic diluent, namely n-butyl glycidyl ether (BGE, JX-013) with a low viscosity, was used to modify diethyl toluene diamine (DETD)-cured diglycidyl ether of bisphenol-F (DGEBF) epoxy system for enhancing cryogenic mechanical properties at liquid nitrogen temperature (77 K). The results showed that the cryogenic strength, ductility and impact resistance (impact strength) have been simultaneously enhanced by the addition of BGE with appropriate contents. Moreover, the comparison of the mechanical properties between 77 K and room temperature (RT) indicated that at the same composition, the tensile strength and Young's modulus at 77 K were higher than those at RT but the failure strain and impact resistance showed the opposite results. Finally, differential scanning calorimetry (DSC) exhibited that the glass transition temperatures (Tg) of the epoxy resins decreased with increasing the BGE content.",
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Simultaneously increasing cryogenic strength, ductility and impact resistance of epoxy resins modified by n-butyl glycidyl ether. / Chen, Zhen Kun; Yang, Guo; Yang, Jiao Ping; Fu, Shao Yun; Ye, Lin; Huang, Yonggang.

In: Polymer, Vol. 50, No. 5, 23.02.2009, p. 1316-1323.

Research output: Contribution to journalArticle

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T1 - Simultaneously increasing cryogenic strength, ductility and impact resistance of epoxy resins modified by n-butyl glycidyl ether

AU - Chen, Zhen Kun

AU - Yang, Guo

AU - Yang, Jiao Ping

AU - Fu, Shao Yun

AU - Ye, Lin

AU - Huang, Yonggang

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Y1 - 2009/2/23

N2 - Epoxy resins are increasingly used in cryogenic engineering areas due to rapid developments of spacecraft and superconducting cable technologies as well as large cryogenic engineering projects (e.g., International Thermonuclear Experimental Reactor). Cryogenic mechanical properties are important parameters for epoxy resins to be employed in such areas. In this paper, a traditional reactive aliphatic diluent, namely n-butyl glycidyl ether (BGE, JX-013) with a low viscosity, was used to modify diethyl toluene diamine (DETD)-cured diglycidyl ether of bisphenol-F (DGEBF) epoxy system for enhancing cryogenic mechanical properties at liquid nitrogen temperature (77 K). The results showed that the cryogenic strength, ductility and impact resistance (impact strength) have been simultaneously enhanced by the addition of BGE with appropriate contents. Moreover, the comparison of the mechanical properties between 77 K and room temperature (RT) indicated that at the same composition, the tensile strength and Young's modulus at 77 K were higher than those at RT but the failure strain and impact resistance showed the opposite results. Finally, differential scanning calorimetry (DSC) exhibited that the glass transition temperatures (Tg) of the epoxy resins decreased with increasing the BGE content.

AB - Epoxy resins are increasingly used in cryogenic engineering areas due to rapid developments of spacecraft and superconducting cable technologies as well as large cryogenic engineering projects (e.g., International Thermonuclear Experimental Reactor). Cryogenic mechanical properties are important parameters for epoxy resins to be employed in such areas. In this paper, a traditional reactive aliphatic diluent, namely n-butyl glycidyl ether (BGE, JX-013) with a low viscosity, was used to modify diethyl toluene diamine (DETD)-cured diglycidyl ether of bisphenol-F (DGEBF) epoxy system for enhancing cryogenic mechanical properties at liquid nitrogen temperature (77 K). The results showed that the cryogenic strength, ductility and impact resistance (impact strength) have been simultaneously enhanced by the addition of BGE with appropriate contents. Moreover, the comparison of the mechanical properties between 77 K and room temperature (RT) indicated that at the same composition, the tensile strength and Young's modulus at 77 K were higher than those at RT but the failure strain and impact resistance showed the opposite results. Finally, differential scanning calorimetry (DSC) exhibited that the glass transition temperatures (Tg) of the epoxy resins decreased with increasing the BGE content.

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