Single-crystal structures of uranium and neptunium oxychalcogenides AnOQ (An=U, Np; Q=S, Se)

Geng Bang Jin, Adam D. Raw, S. Skanthakumar, Richard G. Haire, L. Soderholm, James A Ibers*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

18 Scopus citations

Abstract

The compounds UOS, UOSe, NpOS, and NpOSe have been synthesized and their structures determined by means of single-crystal X-ray diffraction methods. The results provide more detailed crystallographic information, including more precise interatomic distances, than earlier determinations from powder diffraction data. These isostructural compounds adopt the PbFCl structure type. Each An atom is surrounded by four O and five Q atoms in a distorted monocapped square-antiprismatic arrangement.

Original languageEnglish (US)
Pages (from-to)547-550
Number of pages4
JournalJournal of Solid State Chemistry
Volume183
Issue number3
DOIs
StatePublished - Mar 1 2010

Keywords

  • Neptunium oxychalcogenides
  • Single-crystal X-ray structures
  • Uranium oxychalcogenides

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

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