Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection

M. E. Van der Boom; A. G. Richter; J. E. Malinsky; P. A. Lee; N. R. Armstrong; Pulak Dutta; Tobin Jay Marks

doi:10.1021/cm000746w

Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection

M. E. Van der Boom, A. G. Richter, J. E. Malinsky, P. A. Lee, N. R. Armstrong, Pulak Dutta, Tobin Jay Marks^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

53 Scopus citations

Abstract

Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, "one-pot" strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ⁽²⁾_zzz∼220 pm/V and r₃₃∼80 pm/V without electric field poling. This all "wet-chemical self-assembly approach should be readily amenable to automation.

Original language	English (US)
Pages (from-to)	15-17
Number of pages	3
Journal	Chemistry of Materials
Volume	13
Issue number	1
DOIs	https://doi.org/10.1021/cm000746w
State	Published - Mar 6 2001

ASJC Scopus subject areas

General Chemistry
General Chemical Engineering
Materials Chemistry

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title = "Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection",

abstract = "Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, {"}one-pot{"} strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ(2)zzz∼220 pm/V and r33∼80 pm/V without electric field poling. This all {"}wet-chemical self-assembly approach should be readily amenable to automation.",

author = "\{Van der Boom\}, \{M. E.\} and Richter, \{A. G.\} and Malinsky, \{J. E.\} and Lee, \{P. A.\} and Armstrong, \{N. R.\} and Pulak Dutta and Marks, \{Tobin Jay\}",

year = "2001",

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T1 - Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection

AU - Van der Boom, M. E.

AU - Richter, A. G.

AU - Malinsky, J. E.

AU - Lee, P. A.

AU - Armstrong, N. R.

AU - Dutta, Pulak

AU - Marks, Tobin Jay

PY - 2001/3/6

Y1 - 2001/3/6

N2 - Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, "one-pot" strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ(2)zzz∼220 pm/V and r33∼80 pm/V without electric field poling. This all "wet-chemical self-assembly approach should be readily amenable to automation.

AB - Protection-deprotection of silyl-derivatized surface hydroxyl groups represents a new, "one-pot" strategy for the layer-by-layer construction of polar, covalently interlinked electrooptic molecular superlattices. These, siloxane-based multilayer structures are shown to be smooth, adherent, and structurally regular and to exhibit excellent electrooptic/nonlinear optic responses with χ(2)zzz∼220 pm/V and r33∼80 pm/V without electric field poling. This all "wet-chemical self-assembly approach should be readily amenable to automation.

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JF - Chemistry of Materials

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Single reactor route to polar superlattices. Layer-by-layer self-assembly of large-response molecular electrooptic materials by protection-deprotection

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