Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

Rachel C. Klet; Samat Tussupbayev; Joshua Borycz; James R. Gallagher; Madelyn M. Stalzer; Jeffrey T. Miller; Laura Gagliardi; Joseph T. Hupp; Tobin J. Marks; Christopher J. Cramer; Massimiliano Delferro; Omar K. Farha

doi:10.1021/jacs.5b11350

Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

Rachel C. Klet, Samat Tussupbayev, Joshua Borycz, James R. Gallagher, Madelyn M. Stalzer, Jeffrey T. Miller, Laura Gagliardi^*, Joseph T. Hupp, Tobin J. Marks, Christopher J. Cramer, Massimiliano Delferro, Omar K. Farha

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

79 Scopus citations

Abstract

A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d ⁰ Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

Original language	English (US)
Pages (from-to)	15680-15683
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	137
Issue number	50
DOIs	https://doi.org/10.1021/jacs.5b11350
State	Published - Dec 23 2015

ASJC Scopus subject areas

Catalysis
Chemistry(all)
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.5b11350

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Klet, Rachel C. ; Tussupbayev, Samat ; Borycz, Joshua ; Gallagher, James R. ; Stalzer, Madelyn M. ; Miller, Jeffrey T. ; Gagliardi, Laura ; Hupp, Joseph T. ; Marks, Tobin J. ; Cramer, Christopher J. ; Delferro, Massimiliano ; Farha, Omar K. / Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. In: Journal of the American Chemical Society. 2015 ; Vol. 137, No. 50. pp. 15680-15683.

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title = "Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework",

abstract = " A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d 0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization. ",

author = "Klet, {Rachel C.} and Samat Tussupbayev and Joshua Borycz and Gallagher, {James R.} and Stalzer, {Madelyn M.} and Miller, {Jeffrey T.} and Laura Gagliardi and Hupp, {Joseph T.} and Marks, {Tobin J.} and Cramer, {Christopher J.} and Massimiliano Delferro and Farha, {Omar K.}",

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Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework. / Klet, Rachel C.; Tussupbayev, Samat; Borycz, Joshua; Gallagher, James R.; Stalzer, Madelyn M.; Miller, Jeffrey T.; Gagliardi, Laura; Hupp, Joseph T.; Marks, Tobin J.; Cramer, Christopher J.; Delferro, Massimiliano; Farha, Omar K.

In: Journal of the American Chemical Society, Vol. 137, No. 50, 23.12.2015, p. 15680-15683.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

AU - Klet, Rachel C.

AU - Tussupbayev, Samat

AU - Borycz, Joshua

AU - Gallagher, James R.

AU - Stalzer, Madelyn M.

AU - Miller, Jeffrey T.

AU - Gagliardi, Laura

AU - Hupp, Joseph T.

AU - Marks, Tobin J.

AU - Cramer, Christopher J.

AU - Delferro, Massimiliano

AU - Farha, Omar K.

PY - 2015/12/23

Y1 - 2015/12/23

N2 - A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d 0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

AB - A structurally well-defined mesoporous Hf-based metal-organic framework (Hf-NU-1000) is employed as a well-defined scaffold for a highly electrophilic single-site d 0 Zr-benzyl catalytic center. This new material Hf-NU-1000-ZrBn is fully characterized by a variety of spectroscopic techniques and DFT computation. Hf-NU-1000-ZrBn is found to be a promising single-component catalyst (i.e., not requiring a catalyst/activator) for ethylene and stereoregular 1-hexene polymerization.

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JF - Journal of the American Chemical Society

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Single-Site Organozirconium Catalyst Embedded in a Metal-Organic Framework

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