Slippage - An alternative method for assembling [2]rotaxanes

Peter R. Ashton; Martin Bělohradský; Douglas Philp; J. Fraser Stoddart

doi:10.1039/C39930001269

Slippage - An alternative method for assembling [2]rotaxanes

Peter R. Ashton, Martin Bělohradský, Douglas Philp, J. Fraser Stoddart^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

The exploitation of size-complementarity between the macrocyclic component and the stoppers of the dumbbell component of a [2]rotaxane, together with stabilising noncovalent bonding interactions that create a thermodynamic trap, have permitted the development of an alternative method, which can be termed slippage, for the syntheses of [2]rotaxanes in good yields.

Original language	English (US)
Pages (from-to)	1269-1274
Number of pages	6
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	16
DOIs	https://doi.org/10.1039/C39930001269
State	Published - Dec 1 1993

ASJC Scopus subject areas

Molecular Medicine

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10.1039/C39930001269

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title = "Slippage - An alternative method for assembling [2]rotaxanes",

abstract = "The exploitation of size-complementarity between the macrocyclic component and the stoppers of the dumbbell component of a [2]rotaxane, together with stabilising noncovalent bonding interactions that create a thermodynamic trap, have permitted the development of an alternative method, which can be termed slippage, for the syntheses of [2]rotaxanes in good yields.",

author = "Ashton, {Peter R.} and Martin B{\v e}lohradsk{\'y} and Douglas Philp and Stoddart, {J. Fraser}",

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N2 - The exploitation of size-complementarity between the macrocyclic component and the stoppers of the dumbbell component of a [2]rotaxane, together with stabilising noncovalent bonding interactions that create a thermodynamic trap, have permitted the development of an alternative method, which can be termed slippage, for the syntheses of [2]rotaxanes in good yields.

AB - The exploitation of size-complementarity between the macrocyclic component and the stoppers of the dumbbell component of a [2]rotaxane, together with stabilising noncovalent bonding interactions that create a thermodynamic trap, have permitted the development of an alternative method, which can be termed slippage, for the syntheses of [2]rotaxanes in good yields.

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Slippage - An alternative method for assembling [2]rotaxanes

Abstract

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