The exploitation of size-complementarity between the macrocyclic component and the stoppers of the dumbbell component of a rotaxane, together with stabilising noncovalent bonding interactions that create a thermodynamic trap, have permitted the development of an alternative method, which can be termed slippage, for the syntheses of rotaxanes in good yields.
|Original language||English (US)|
|Number of pages||6|
|Journal||Journal of the Chemical Society, Chemical Communications|
|State||Published - 1993|
ASJC Scopus subject areas
- Molecular Medicine