SnTe-AgBiTe2 as an efficient thermoelectric material with low thermal conductivity

Gangjian Tan, Fengyuan Shi, Hui Sun, Li Dong Zhao, Ctirad Uher, Vinayak P. Dravid, Mercouri G. Kanatzidis*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

132 Scopus citations


SnTe is an intriguing alternative to its sister compound PbTe in thermoelectric energy conversion because of their electronic and structural similarity; however, it is challenging to optimize its thermoelectric performance to the level of PbTe because of the difficulties in decreasing its intrinsically large hole population and high thermal conductivity arising from the tin vacancies. We demonstrate here that by alloying some AgBiTe2 in SnTe, thus forming AgSnxBiTex+2 compositions the hole concentration can be duly decreased because of the high efficiency of Bi as an electron donor. The lattice thermal conductivity is also decreased due to the strong scattering of phonons (by point defect scattering as well as Ag-rich nanostructures) to achieve a value of ∼0.7 W m-1 K-1 at ∼750 K. As a result, a high thermoelectric figure ZT of merit of ∼1.1 at 775 K is achieved by chemical composition optimization (×∼15), making lead free SnTe-AgBiTe2 a promising thermoelectric material.

Original languageEnglish (US)
Pages (from-to)20849-20854
Number of pages6
JournalJournal of Materials Chemistry A
Issue number48
StatePublished - Dec 28 2014

ASJC Scopus subject areas

  • Chemistry(all)
  • Renewable Energy, Sustainability and the Environment
  • Materials Science(all)


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