{Sn[Zn4Sn4S17]}6-: A robust open framework based on metal-linked penta-supertetrahedral [Zn 4Sn4S17]10- clusters with ion-exchange properties

Manolis J. Manos; Ratnasabapathy G. Iyer; Eric Quarez; J. H. Liao; Mercouri G. Kanatzidis

doi:10.1002/anie.200500214

{Sn[Zn₄Sn₄S₁₇]}^6-: A robust open framework based on metal-linked penta-supertetrahedral [Zn ₄Sn₄S₁₇]^10- clusters with ion-exchange properties

Manolis J. Manos^*, Ratnasabapathy G. Iyer, Eric Quarez, J. H. Liao, Mercouri G. Kanatzidis

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

169 Scopus citations

Abstract

(Chemical Equation Presented) Like zeolites, K₆Sn[Zn ₄Sn₄S₁₇] (see structure) has remarkable ion-exchange properties and forms CsK₅Sn[Zn₄Sn ₄S₁₇] and RbK₅Sn[Zn₄Sn ₄S₁₇] in the presence of the Cs⁺ and Rb ⁺ ions, respectively. These compounds have an open framework comprising [Zn₄Sn₄S₁₇]^10- clusters linked by Sn⁴⁺ centers and are remarkably stable. One-fifth of the K⁺ ions play an important templating role in stabilizing the framework. Zn blue, Sn red, S yellow, K orange.

Original language	English (US)
Pages (from-to)	3552-3555
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	44
Issue number	23
DOIs	https://doi.org/10.1002/anie.200500214
State	Published - Jun 6 2005

Keywords

Cluster compounds
Ion exchange
Nonlinear optics
Semiconductors
Zeolites

ASJC Scopus subject areas

Catalysis
Chemistry(all)

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10.1002/anie.200500214

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@article{218d2225961a4232a64723c78e5b1fd0,

title = "{Sn[Zn4Sn4S17]}6-: A robust open framework based on metal-linked penta-supertetrahedral [Zn 4Sn4S17]10- clusters with ion-exchange properties",

abstract = "(Chemical Equation Presented) Like zeolites, K6Sn[Zn 4Sn4S17] (see structure) has remarkable ion-exchange properties and forms CsK5Sn[Zn4Sn 4S17] and RbK5Sn[Zn4Sn 4S17] in the presence of the Cs+ and Rb + ions, respectively. These compounds have an open framework comprising [Zn4Sn4S17]10- clusters linked by Sn4+ centers and are remarkably stable. One-fifth of the K+ ions play an important templating role in stabilizing the framework. Zn blue, Sn red, S yellow, K orange.",

keywords = "Cluster compounds, Ion exchange, Nonlinear optics, Semiconductors, Zeolites",

author = "Manos, {Manolis J.} and Iyer, {Ratnasabapathy G.} and Eric Quarez and Liao, {J. H.} and Kanatzidis, {Mercouri G.}",

year = "2005",

month = jun,

day = "6",

doi = "10.1002/anie.200500214",

language = "English (US)",

volume = "44",

pages = "3552--3555",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "23",

}

{Sn[Zn₄Sn₄S₁₇]}^6- : A robust open framework based on metal-linked penta-supertetrahedral [Zn ₄Sn₄S₁₇]^10- clusters with ion-exchange properties. / Manos, Manolis J.; Iyer, Ratnasabapathy G.; Quarez, Eric; Liao, J. H.; Kanatzidis, Mercouri G.

In: Angewandte Chemie - International Edition, Vol. 44, No. 23, 06.06.2005, p. 3552-3555.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - {Sn[Zn4Sn4S17]}6-

T2 - A robust open framework based on metal-linked penta-supertetrahedral [Zn 4Sn4S17]10- clusters with ion-exchange properties

AU - Manos, Manolis J.

AU - Iyer, Ratnasabapathy G.

AU - Quarez, Eric

AU - Liao, J. H.

AU - Kanatzidis, Mercouri G.

PY - 2005/6/6

Y1 - 2005/6/6

N2 - (Chemical Equation Presented) Like zeolites, K6Sn[Zn 4Sn4S17] (see structure) has remarkable ion-exchange properties and forms CsK5Sn[Zn4Sn 4S17] and RbK5Sn[Zn4Sn 4S17] in the presence of the Cs+ and Rb + ions, respectively. These compounds have an open framework comprising [Zn4Sn4S17]10- clusters linked by Sn4+ centers and are remarkably stable. One-fifth of the K+ ions play an important templating role in stabilizing the framework. Zn blue, Sn red, S yellow, K orange.

AB - (Chemical Equation Presented) Like zeolites, K6Sn[Zn 4Sn4S17] (see structure) has remarkable ion-exchange properties and forms CsK5Sn[Zn4Sn 4S17] and RbK5Sn[Zn4Sn 4S17] in the presence of the Cs+ and Rb + ions, respectively. These compounds have an open framework comprising [Zn4Sn4S17]10- clusters linked by Sn4+ centers and are remarkably stable. One-fifth of the K+ ions play an important templating role in stabilizing the framework. Zn blue, Sn red, S yellow, K orange.

KW - Cluster compounds

KW - Ion exchange

KW - Nonlinear optics

KW - Semiconductors

KW - Zeolites

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