TY - GEN
T1 - Solving problems with biobased, sustainable PLA and recyclability of PET for high-value applications via solid-state shear pulverization
AU - Torkelson, John M.
AU - Brunner, Philip J.
AU - Pierre, Cynthia
AU - Millard-Swan, Alexander
AU - Pukala, Kevin
PY - 2010
Y1 - 2010
N2 - Abstract:Solid-state shear pulverization (SSSP) can lead to in situ mechanochemistry and enhanced dispersion relative to melt-state processes. SSSP of poly(ethylene terephthalate) (PET) results in low levels of branching and enhanced dispersion of heterogeneous nuclei, leading to increased melt viscosity and crystallizability, providing a solution to the problem of recycling PET for high-value applications. (PET undergoes molecular weight reduction during melt processing.) Adding 1 wt% microcrystalline cellulose to poly(lactic acid) (PLA) via SSSP can lead to major enhancements in crystallizability and materials with increased heat distortion temperature relative to neat PLA.
AB - Abstract:Solid-state shear pulverization (SSSP) can lead to in situ mechanochemistry and enhanced dispersion relative to melt-state processes. SSSP of poly(ethylene terephthalate) (PET) results in low levels of branching and enhanced dispersion of heterogeneous nuclei, leading to increased melt viscosity and crystallizability, providing a solution to the problem of recycling PET for high-value applications. (PET undergoes molecular weight reduction during melt processing.) Adding 1 wt% microcrystalline cellulose to poly(lactic acid) (PLA) via SSSP can lead to major enhancements in crystallizability and materials with increased heat distortion temperature relative to neat PLA.
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M3 - Conference contribution
AN - SCOPUS:77956718572
SN - 9781617386602
T3 - Annual Technical Conference - ANTEC, Conference Proceedings
SP - 1481
EP - 1485
BT - 68th Annual Technical Conference of the Society of Plastics Engineers 2010, ANTEC 2010
T2 - 68th Annual Technical Conference of the Society of Plastics Engineers 2010, ANTEC 2010
Y2 - 16 May 2010 through 20 May 2010
ER -