Solvothermal synthesis route to ternary chalcogenides Cu(Ag)-Pd-S

Bin Li; Yi Xie; Jiaxing Huang; Yu Liu; Yitai Qian

doi:10.1016/S1387-7003(00)00109-X

Solvothermal synthesis route to ternary chalcogenides Cu(Ag)-Pd-S

Bin Li, Yi Xie^*, Jiaxing Huang, Yu Liu, Yitai Qian

^*Corresponding author for this work

Materials Science and Engineering

Research output: Contribution to journal › Article › peer-review

7 Scopus citations

Abstract

A mild route to ternary chalcogenidometalates Cu₃Pd₁₃S₇ and Ag₅Pd₁₀S₅ nanocrystals is proposed in this paper. Both compounds can be directly synthesized from the reaction of PdCl₂, sulfur and CuCl₂ or AgNO₃ through solvothermal processes in diethylamine or ethylenediamine (en) at 140-160°C for 10 h. The final products have been characterized by X-ray diffraction (XRD) patterns, transmission electron microscope (TEM) images, and X-ray photoelectron spectra (XPS). The formation mechanism of the nanocrystalline ternary chalcogenidometalates in the solvothermal process is also investigated. (C) 2000 Elsevier Science S.A.

Original language	English (US)
Pages (from-to)	462-464
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	3
Issue number	9
DOIs	https://doi.org/10.1016/S1387-7003(00)00109-X
State	Published - 2000

Keywords

Alkylamine
Nanocrystals
Solvothermal
Ternary chalcogenides

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry
Materials Chemistry

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10.1016/S1387-7003(00)00109-X

Cite this

@article{94c617f3bfd9434b8bfa66173d9f7188,

title = "Solvothermal synthesis route to ternary chalcogenides Cu(Ag)-Pd-S",

abstract = "A mild route to ternary chalcogenidometalates Cu3Pd13S7 and Ag5Pd10S5 nanocrystals is proposed in this paper. Both compounds can be directly synthesized from the reaction of PdCl2, sulfur and CuCl2 or AgNO3 through solvothermal processes in diethylamine or ethylenediamine (en) at 140-160°C for 10 h. The final products have been characterized by X-ray diffraction (XRD) patterns, transmission electron microscope (TEM) images, and X-ray photoelectron spectra (XPS). The formation mechanism of the nanocrystalline ternary chalcogenidometalates in the solvothermal process is also investigated. (C) 2000 Elsevier Science S.A.",

keywords = "Alkylamine, Nanocrystals, Solvothermal, Ternary chalcogenides",

author = "Bin Li and Yi Xie and Jiaxing Huang and Yu Liu and Yitai Qian",

note = "Funding Information: Financial support from the Chinese National Foundation of Natural Sciences and the Chinese Ministry of Education are gratefully acknowledged.",

year = "2000",

doi = "10.1016/S1387-7003(00)00109-X",

language = "English (US)",

volume = "3",

pages = "462--464",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier BV",

number = "9",

}

TY - JOUR

T1 - Solvothermal synthesis route to ternary chalcogenides Cu(Ag)-Pd-S

AU - Li, Bin

AU - Xie, Yi

AU - Huang, Jiaxing

AU - Liu, Yu

AU - Qian, Yitai

N1 - Funding Information: Financial support from the Chinese National Foundation of Natural Sciences and the Chinese Ministry of Education are gratefully acknowledged.

PY - 2000

Y1 - 2000

N2 - A mild route to ternary chalcogenidometalates Cu3Pd13S7 and Ag5Pd10S5 nanocrystals is proposed in this paper. Both compounds can be directly synthesized from the reaction of PdCl2, sulfur and CuCl2 or AgNO3 through solvothermal processes in diethylamine or ethylenediamine (en) at 140-160°C for 10 h. The final products have been characterized by X-ray diffraction (XRD) patterns, transmission electron microscope (TEM) images, and X-ray photoelectron spectra (XPS). The formation mechanism of the nanocrystalline ternary chalcogenidometalates in the solvothermal process is also investigated. (C) 2000 Elsevier Science S.A.

AB - A mild route to ternary chalcogenidometalates Cu3Pd13S7 and Ag5Pd10S5 nanocrystals is proposed in this paper. Both compounds can be directly synthesized from the reaction of PdCl2, sulfur and CuCl2 or AgNO3 through solvothermal processes in diethylamine or ethylenediamine (en) at 140-160°C for 10 h. The final products have been characterized by X-ray diffraction (XRD) patterns, transmission electron microscope (TEM) images, and X-ray photoelectron spectra (XPS). The formation mechanism of the nanocrystalline ternary chalcogenidometalates in the solvothermal process is also investigated. (C) 2000 Elsevier Science S.A.

KW - Alkylamine

KW - Nanocrystals

KW - Solvothermal

KW - Ternary chalcogenides

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U2 - 10.1016/S1387-7003(00)00109-X

DO - 10.1016/S1387-7003(00)00109-X

M3 - Article

AN - SCOPUS:0033833764

SN - 1387-7003

VL - 3

SP - 462

EP - 464

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

IS - 9

ER -

Solvothermal synthesis route to ternary chalcogenides Cu(Ag)-Pd-S

Abstract

Keywords

ASJC Scopus subject areas

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