Spectroscopy and reaction kinetics of photolytically generated fe(co)x (x = 2,3,4)

A. J. Ouderkirk, T. A. Seder, Eric Weitz

Research output: Contribution to journalArticlepeer-review

9 Scopus citations

Abstract

An apparatus for the gas phase infrared spectroscopic detection of coordinatively un-saturated metal carbonyls is described. Coordinatively unsaturated species are produced by UV photolysis. Infrared spectra of coordinatively unsaturated iron carbonyls are reported for the carbonyl stretch region. Rate constants for the reaction of Fe(CO)3 and Fe(CO)4 with CO are also reported. The photophysics of Fe(CO)x formation is discussed.

Original languageEnglish (US)
Pages (from-to)148-153
Number of pages6
JournalProceedings of SPIE - The International Society for Optical Engineering
Volume458
DOIs
StatePublished - May 31 1984

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics
  • Computer Science Applications
  • Applied Mathematics
  • Electrical and Electronic Engineering

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