Spectroscopy and reaction kinetics of photolytically generated fe(co)x (x = 2,3,4)

A. J. Ouderkirk; T. A. Seder; Eric Weitz

doi:10.1117/12.939425

Spectroscopy and reaction kinetics of photolytically generated fe(co)x (x = 2,3,4)

A. J. Ouderkirk, T. A. Seder, Eric Weitz

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

An apparatus for the gas phase infrared spectroscopic detection of coordinatively un-saturated metal carbonyls is described. Coordinatively unsaturated species are produced by UV photolysis. Infrared spectra of coordinatively unsaturated iron carbonyls are reported for the carbonyl stretch region. Rate constants for the reaction of Fe(CO)3 and Fe(CO)4 with CO are also reported. The photophysics of Fe(CO)x formation is discussed.

Original language	English (US)
Pages (from-to)	148-153
Number of pages	6
Journal	Proceedings of SPIE - The International Society for Optical Engineering
Volume	458
DOIs	https://doi.org/10.1117/12.939425
State	Published - May 31 1984

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Computer Science Applications
Applied Mathematics
Electrical and Electronic Engineering

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title = "Spectroscopy and reaction kinetics of photolytically generated fe(co)x (x = 2,3,4)",

abstract = "An apparatus for the gas phase infrared spectroscopic detection of coordinatively un-saturated metal carbonyls is described. Coordinatively unsaturated species are produced by UV photolysis. Infrared spectra of coordinatively unsaturated iron carbonyls are reported for the carbonyl stretch region. Rate constants for the reaction of Fe(CO)3 and Fe(CO)4 with CO are also reported. The photophysics of Fe(CO)x formation is discussed.",

author = "Ouderkirk, {A. J.} and Seder, {T. A.} and Eric Weitz",

year = "1984",

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T1 - Spectroscopy and reaction kinetics of photolytically generated fe(co)x (x = 2,3,4)

AU - Ouderkirk, A. J.

AU - Seder, T. A.

AU - Weitz, Eric

PY - 1984/5/31

Y1 - 1984/5/31

N2 - An apparatus for the gas phase infrared spectroscopic detection of coordinatively un-saturated metal carbonyls is described. Coordinatively unsaturated species are produced by UV photolysis. Infrared spectra of coordinatively unsaturated iron carbonyls are reported for the carbonyl stretch region. Rate constants for the reaction of Fe(CO)3 and Fe(CO)4 with CO are also reported. The photophysics of Fe(CO)x formation is discussed.

AB - An apparatus for the gas phase infrared spectroscopic detection of coordinatively un-saturated metal carbonyls is described. Coordinatively unsaturated species are produced by UV photolysis. Infrared spectra of coordinatively unsaturated iron carbonyls are reported for the carbonyl stretch region. Rate constants for the reaction of Fe(CO)3 and Fe(CO)4 with CO are also reported. The photophysics of Fe(CO)x formation is discussed.

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JO - Proceedings of SPIE - The International Society for Optical Engineering

JF - Proceedings of SPIE - The International Society for Optical Engineering

ER -

Spectroscopy and reaction kinetics of photolytically generated fe(co)x (x = 2,3,4)

Abstract

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