Spectroscopy of high vibrational levels of the N-N stretching mode of N-N-16O and N-N-18O

N. L.S. Yamasaki; Carlos Manzanares I.; L. C. Baylor; G. C. Schatz; Eric Weitz

doi:10.1021/j100343a007

Spectroscopy of high vibrational levels of the N-N stretching mode of N-N-¹⁶O and N-N-¹⁸O

N. L.S. Yamasaki, Carlos Manzanares I., L. C. Baylor, G. C. Schatz^*, Eric Weitz

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

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Abstract

The fundamental and overtones up to v = 6 of the v₃ mode of N₂¹⁶O and N₂¹⁸O have been studied. The positions of the v₃ overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-consistent field and configuration interaction calculations and isotopic shift data show that the N-N stretching overtone is best described as a normal mode. Both N₂¹⁶O and N₂¹⁸O display line widths for the R branch of the v = 6 overtone of less than 2 cm^-1.

Original language	English (US)
Pages (from-to)	2204-2209
Number of pages	6
Journal	Journal of physical chemistry
Volume	93
Issue number	6
DOIs	https://doi.org/10.1021/j100343a007
State	Published - 1989

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General Engineering
Physical and Theoretical Chemistry

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@article{e56a462070484cf199d485d9f317f2e8,

title = "Spectroscopy of high vibrational levels of the N-N stretching mode of N-N-16O and N-N-18O",

abstract = "The fundamental and overtones up to v = 6 of the v3 mode of N216O and N218O have been studied. The positions of the v3 overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-consistent field and configuration interaction calculations and isotopic shift data show that the N-N stretching overtone is best described as a normal mode. Both N216O and N218O display line widths for the R branch of the v = 6 overtone of less than 2 cm-1.",

author = "Yamasaki, {N. L.S.} and {Manzanares I.}, Carlos and Baylor, {L. C.} and Schatz, {G. C.} and Eric Weitz",

year = "1989",

doi = "10.1021/j100343a007",

language = "English (US)",

volume = "93",

pages = "2204--2209",

journal = "Journal of physical chemistry",

issn = "0022-3654",

publisher = "American Chemical Society",

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T1 - Spectroscopy of high vibrational levels of the N-N stretching mode of N-N-16O and N-N-18O

AU - Yamasaki, N. L.S.

AU - Manzanares I., Carlos

AU - Baylor, L. C.

AU - Schatz, G. C.

AU - Weitz, Eric

PY - 1989

Y1 - 1989

N2 - The fundamental and overtones up to v = 6 of the v3 mode of N216O and N218O have been studied. The positions of the v3 overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-consistent field and configuration interaction calculations and isotopic shift data show that the N-N stretching overtone is best described as a normal mode. Both N216O and N218O display line widths for the R branch of the v = 6 overtone of less than 2 cm-1.

AB - The fundamental and overtones up to v = 6 of the v3 mode of N216O and N218O have been studied. The positions of the v3 overtones can be fit by a two-parameter model since there is very limited interaction with other molecular vibrations. Vibrational self-consistent field and configuration interaction calculations and isotopic shift data show that the N-N stretching overtone is best described as a normal mode. Both N216O and N218O display line widths for the R branch of the v = 6 overtone of less than 2 cm-1.

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JO - Journal of physical chemistry

JF - Journal of physical chemistry

IS - 6

ER -

Spectroscopy of high vibrational levels of the N-N stretching mode of N-N-¹⁶O and N-N-¹⁸O

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