Abstract
We report the fabrication of high-performance organic field-effect transistors (OFETs) and complementary inverters using spray-printed films of n-type small-molecule semiconductors and p-type conjugated polymers. Highly crystalline organic semiconductor films could be obtained by controlling the droplet size, nozzle-to-substrate distance, and solvent drying speed during the printing process. After the optimisation of the spray-printing process, the performances of the spray-printed OFETs were comparable to those of spin-coated and inkjet-printed OFETs. In addition to excellent device-to-device uniformity, the spray-printed n- and p-channel OFETs also exhibited high field-effect mobilities, which were ∼0.3 (ActivInk™ N1450, Polyera), ∼0.01 (regioregular-poly(3-hexylthiophene) (rr-P3HT)), and ∼0.25 cm2 V-1 s-1 (ActivInk™ P2100, Polyera). Organic complementary inverters were fabricated by spray printing and shadow-mask patterning while using ActivInk™ N1450 and P2100 as the n- and p-type semiconductors, respectively. The complementary inverters exhibited a large voltage gain (∼17) and a low power consumption (∼0.02 mW) at V DD = 60 V.
Original language | English (US) |
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Pages (from-to) | 1500-1506 |
Number of pages | 7 |
Journal | Journal of Materials Chemistry C |
Volume | 1 |
Issue number | 7 |
DOIs | |
State | Published - Feb 21 2013 |
ASJC Scopus subject areas
- General Chemistry
- Materials Chemistry