State-selected reaction of muonium with vibrationally excited H 2

Pavel Bakule, Donald G. Fleming*, Oleksandr Sukhorukov, Katsuhiko Ishida, Francis Pratt, Takamasa Momose, Eiko Torikai, Steven L. Mielke, Bruce C. Garrett, Kirk A. Peterson, George C. Schatz, Donald G. Truhlar

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

22 Scopus citations

Abstract

We report a new advance in the study of muonium (Mu) reactivity; specifically, we report the rate constant for the Mu + H 2(vibrational quantum number n = 1) reaction determined by measurements at 300 K and by converged quantum mechanical calculations. Comparisons are made with earlier results for D + H 2 (n = 1) and with the corresponding thermal reaction rates. The measurements are a sensitive probe of the high-curvature region in the entrance valley of the potential energy surface (PES) and thus provide a qualitatively different probe of the PES than that provided by any previous experiment.

Original languageEnglish (US)
Pages (from-to)2755-2760
Number of pages6
JournalJournal of Physical Chemistry Letters
Volume3
Issue number19
DOIs
StatePublished - Oct 4 2012

ASJC Scopus subject areas

  • Materials Science(all)
  • Physical and Theoretical Chemistry

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