Stepwise assembly of coordination-based metal-organic networks

Revital Kaminker; Leila Motiei; Antonino Gulino; Ignazio Fragalà; Linda J.W. Shimon; Guennadi Evmenenko; Pulak Dutta; Mark A. Iron; Milko E. Van Der Boom

doi:10.1021/ja105518n

Stepwise assembly of coordination-based metal-organic networks

Revital Kaminker, Leila Motiei, Antonino Gulino, Ignazio Fragalà, Linda J.W. Shimon, Guennadi Evmenenko, Pulak Dutta, Mark A. Iron, Milko E. Van Der Boom

Physics and Astronomy

Research output: Contribution to journal › Article › peer-review

55 Scopus citations

Abstract

Metal-organic networks (MONs) were created by a stepwise solution deposition approach from vinylpyridine-based building blocks and PdCl ₂. The combined experimental and computational study demonstrates the formation of saturated, structurally organized systems on solid supports. The rigid nature and geometry of the components are well-suited to form honeycomb and parallelogram structures, as predicted by a computational study. Detailed structural information of the new MONs was obtained by optical (UV/vis) spectroscopy, ellipsometry, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and synchrotron X-ray reflectivity (XRR). Notably, the XPS elemental composition indicates the formation of a palladium coordination-based network.

Original language	English (US)
Pages (from-to)	14554-14561
Number of pages	8
Journal	Journal of the American Chemical Society
Volume	132
Issue number	41
DOIs	https://doi.org/10.1021/ja105518n
State	Published - Oct 20 2010

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

Access to Document

10.1021/ja105518n

Cite this

@article{ed2c0e578f2445bcb8fd38cc5939e626,

title = "Stepwise assembly of coordination-based metal-organic networks",

abstract = "Metal-organic networks (MONs) were created by a stepwise solution deposition approach from vinylpyridine-based building blocks and PdCl 2. The combined experimental and computational study demonstrates the formation of saturated, structurally organized systems on solid supports. The rigid nature and geometry of the components are well-suited to form honeycomb and parallelogram structures, as predicted by a computational study. Detailed structural information of the new MONs was obtained by optical (UV/vis) spectroscopy, ellipsometry, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and synchrotron X-ray reflectivity (XRR). Notably, the XPS elemental composition indicates the formation of a palladium coordination-based network.",

author = "Revital Kaminker and Leila Motiei and Antonino Gulino and Ignazio Fragal{\`a} and Shimon, {Linda J.W.} and Guennadi Evmenenko and Pulak Dutta and Iron, {Mark A.} and {Van Der Boom}, {Milko E.}",

year = "2010",

month = oct,

day = "20",

doi = "10.1021/ja105518n",

language = "English (US)",

volume = "132",

pages = "14554--14561",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "41",

}

TY - JOUR

T1 - Stepwise assembly of coordination-based metal-organic networks

AU - Kaminker, Revital

AU - Motiei, Leila

AU - Gulino, Antonino

AU - Fragalà, Ignazio

AU - Shimon, Linda J.W.

AU - Evmenenko, Guennadi

AU - Dutta, Pulak

AU - Iron, Mark A.

AU - Van Der Boom, Milko E.

PY - 2010/10/20

Y1 - 2010/10/20

N2 - Metal-organic networks (MONs) were created by a stepwise solution deposition approach from vinylpyridine-based building blocks and PdCl 2. The combined experimental and computational study demonstrates the formation of saturated, structurally organized systems on solid supports. The rigid nature and geometry of the components are well-suited to form honeycomb and parallelogram structures, as predicted by a computational study. Detailed structural information of the new MONs was obtained by optical (UV/vis) spectroscopy, ellipsometry, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and synchrotron X-ray reflectivity (XRR). Notably, the XPS elemental composition indicates the formation of a palladium coordination-based network.

AB - Metal-organic networks (MONs) were created by a stepwise solution deposition approach from vinylpyridine-based building blocks and PdCl 2. The combined experimental and computational study demonstrates the formation of saturated, structurally organized systems on solid supports. The rigid nature and geometry of the components are well-suited to form honeycomb and parallelogram structures, as predicted by a computational study. Detailed structural information of the new MONs was obtained by optical (UV/vis) spectroscopy, ellipsometry, atomic force microscopy (AFM), X-ray photoelectron spectroscopy (XPS), and synchrotron X-ray reflectivity (XRR). Notably, the XPS elemental composition indicates the formation of a palladium coordination-based network.

UR - http://www.scopus.com/inward/record.url?scp=77958027974&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=77958027974&partnerID=8YFLogxK

U2 - 10.1021/ja105518n

DO - 10.1021/ja105518n

M3 - Article

C2 - 20863123

AN - SCOPUS:77958027974

SN - 0002-7863

VL - 132

SP - 14554

EP - 14561

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 41

ER -

Stepwise assembly of coordination-based metal-organic networks

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 768612: Experimental Crystal Structure Determination

Cite this

Stepwise assembly of coordination-based metal-organic networks

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 768612: Experimental Crystal Structure Determination

Cite this