Stereoselection Effects in the Catalytic Hydroamination/Cyclization of Amino olefins at Chiral Organolanthanide Centers

Michel R. Gagné, Laurent Brard, Vincent P. Conticello, Michael A. Giardello, Charlotte L. Stern, Tobin Jay Marks*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

189 Scopus citations

Abstract

The chiral organolanthanide complexes Me2Si(Me4C5)(C5H3R*)LnE(SiMe3)2 (R* = (-)-menthyl, (+)-neomenthyl; Ln = La, Sm; E = N, CH) serve as precatalysts for the enantloselectlve or dlastereoselectlve hydroaminatlon/cyclization of aminoolefins to chiral pyrrolidines and piperidines.

Original languageEnglish (US)
Pages (from-to)2003-2005
Number of pages3
JournalOrganometallics
Volume11
Issue number6
DOIs
StatePublished - Jun 1 1992

ASJC Scopus subject areas

  • Physical and Theoretical Chemistry
  • Organic Chemistry
  • Inorganic Chemistry

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