Stereoselective synthesis of dienes from N-allylhydrazones

Devon A. Mundal; Kelly E. Lutz; Regan James Thomson

doi:10.1021/ol802585r

Stereoselective synthesis of dienes from N-allylhydrazones

Devon A. Mundal^*, Kelly E. Lutz, Regan James Thomson

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

61 Scopus citations

Abstract

(Chemical Equation Presented) A new method for the stereoselective synthesis of dienes from aldehydes and N-allylhydrazine derivatives has been developed. High levels of (E)-stereoselectivity are obtained for a variety of substrates. Addition of a dienophile to the reaction mixture allows a one-flask diene synthesis-cycloaddition sequence.

Original language	English (US)
Pages (from-to)	465-468
Number of pages	4
Journal	Organic Letters
Volume	11
Issue number	2
DOIs	https://doi.org/10.1021/ol802585r
State	Published - Jan 15 2009

ASJC Scopus subject areas

Organic Chemistry
Physical and Theoretical Chemistry
Biochemistry

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10.1021/ol802585r

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title = "Stereoselective synthesis of dienes from N-allylhydrazones",

abstract = "(Chemical Equation Presented) A new method for the stereoselective synthesis of dienes from aldehydes and N-allylhydrazine derivatives has been developed. High levels of (E)-stereoselectivity are obtained for a variety of substrates. Addition of a dienophile to the reaction mixture allows a one-flask diene synthesis-cycloaddition sequence.",

author = "Mundal, {Devon A.} and Lutz, {Kelly E.} and Thomson, {Regan James}",

year = "2009",

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AU - Lutz, Kelly E.

AU - Thomson, Regan James

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Y1 - 2009/1/15

N2 - (Chemical Equation Presented) A new method for the stereoselective synthesis of dienes from aldehydes and N-allylhydrazine derivatives has been developed. High levels of (E)-stereoselectivity are obtained for a variety of substrates. Addition of a dienophile to the reaction mixture allows a one-flask diene synthesis-cycloaddition sequence.

AB - (Chemical Equation Presented) A new method for the stereoselective synthesis of dienes from aldehydes and N-allylhydrazine derivatives has been developed. High levels of (E)-stereoselectivity are obtained for a variety of substrates. Addition of a dienophile to the reaction mixture allows a one-flask diene synthesis-cycloaddition sequence.

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Stereoselective synthesis of dienes from N-allylhydrazones

Abstract

ASJC Scopus subject areas

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