Steric control of the donor/acceptor interface: Implications in organic photovoltaic charge generation

Thomas W. Holcombe, Joseph E. Norton, Jonathan Rivnay, Claire H. Woo, Ludwig Goris, Claudia Piliego, Gianmarco Griffini, Alan Sellinger, Jean Luc Brédas, Alberto Salleo, Jean M J Fréchet

Research output: Contribution to journalArticlepeer-review

188 Scopus citations


The performance of organic photovoltaic (OPV) devices is currently limited by modest short-circuit current densities. Approaches toward improving this output parameter may provide new avenues to advance OPV technologies and the basic science of charge transfer in organic semiconductors. This work highlights how steric control of the charge separation interface can be effectively tuned in OPV devices. By introducing an octylphenyl substituent onto the investigated polymer backbones, the thermally relaxed charge-transfer state, and potentially excited charge-transfer states, can be raised in energy. This decreases the barrier to charge separation and results in increased photocurrent generation. This finding is of particular significance for nonfullerene OPVs, which have many potential advantages such as tunable energy levels and spectral breadth, but are prone to poor exciton separation efficiencies. Computational, spectroscopic, and synthetic methods were combined to develop a structure-property relationship that correlates polymer substituents with charge-transfer state energies and, ultimately, device efficiencies.

Original languageEnglish (US)
Pages (from-to)12106-12114
Number of pages9
JournalJournal of the American Chemical Society
Issue number31
StatePublished - Aug 10 2011

ASJC Scopus subject areas

  • Catalysis
  • Chemistry(all)
  • Biochemistry
  • Colloid and Surface Chemistry


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