Stochastic theory of collisional energy transfer: nature of convergence of master equation transition probabilities and moments as a function of cumulant expansion order

George C. Schatz

doi:10.1016/0009-2614(78)85055-6

Stochastic theory of collisional energy transfer: nature of convergence of master equation transition probabilities and moments as a function of cumulant expansion order

George C. Schatz^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

11 Scopus citations

Abstract

Closed form expressions for collisional energy transfer transition probabilities and moments are determined for the forced oscillator model by solving cumulant expansion master equation in second, fourth, sixth and infinite order. This enables a study of convergence properties of the cumulant expansion.

Original language	English (US)
Pages (from-to)	368-374
Number of pages	7
Journal	Chemical Physics Letters
Volume	58
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(78)85055-6
State	Published - Oct 1 1978

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Stochastic theory of collisional energy transfer: nature of convergence of master equation transition probabilities and moments as a function of cumulant expansion order",

abstract = "Closed form expressions for collisional energy transfer transition probabilities and moments are determined for the forced oscillator model by solving cumulant expansion master equation in second, fourth, sixth and infinite order. This enables a study of convergence properties of the cumulant expansion.",

author = "Schatz, {George C.}",

year = "1978",

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N2 - Closed form expressions for collisional energy transfer transition probabilities and moments are determined for the forced oscillator model by solving cumulant expansion master equation in second, fourth, sixth and infinite order. This enables a study of convergence properties of the cumulant expansion.

AB - Closed form expressions for collisional energy transfer transition probabilities and moments are determined for the forced oscillator model by solving cumulant expansion master equation in second, fourth, sixth and infinite order. This enables a study of convergence properties of the cumulant expansion.

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