Strategie synthesis of 2,6-pyridylene-bridged β-to-β porphyrin nanorings through cross-coupling

Jianxin Song, Pyosang Kim, Naoki Aratani, Dongho Kim*, Hiroshi Shinokubo, Atsuhiro Osuka

*Corresponding author for this work

Research output: Contribution to journalArticle

19 Scopus citations

Abstract

(Figure Presented) The bridge determines the size of the loop? Palladium-catalyzed cross-coupling of borylporphyrins led to the construction of β-pyridine-bridged porphyrin nanorings in good yields (around 55-60 % ; see scheme). The photophysical study revealed that these nanorings exhibit weakly coupled chromophores and longer fluorescent lifetimes, which is an apparent advantage in the process of efficient excited energy transfer.

Original languageEnglish (US)
Pages (from-to)3009-3012
Number of pages4
JournalChemistry - A European Journal
Volume16
Issue number10
DOIs
StatePublished - Mar 8 2010

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Keywords

  • Cross-coupling
  • Fluorescence
  • Host-guest chemistry
  • Nanorings
  • Porphyrinoids

ASJC Scopus subject areas

  • Chemistry(all)

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