Strengthening mechanisms in Al–Ni–Sc alloys containing Al3Ni microfibers and Al3Sc nanoprecipitates

C. Suwanpreecha, J. Perrin Toinin, R. A. Michi, P. Pandee, David C Dunand, C. Limmaneevichitr

Research output: Contribution to journalArticle

Abstract

Dilute Al–Sc alloys (<0.4 wt% Sc) are creep-resistant up to ∼300 °C owing to coherent, nanosize Al3Sc particles created by solid-state precipitation. By contrast, eutectic Al–Ni alloys (Al-6 wt.% Ni) derive their high strength at elevated temperature from Al3Ni microfibers formed during solidification. Here, we investigate ternary Al–6Ni-0.2Sc and Al–6Ni-0.4Sc alloys with both types of strengthening precipitates (Al3Sc and Al3Ni) and compare them to binary Al–6Ni, Al-0.2Sc and Al-0.4Sc alloys with a single population of precipitates. Kinetics of Al3Sc and Al3Ni precipitation and coarsening are studied via hardness measurements during isochronal and isothermal aging; the two phases resist coarsening up to 475 and 350 °C, respectively, upon short term exposures (1 h isochronal steps). No noticeable effect of Sc is observed on the Al3Ni micro-fiber composition and hardening in the alloy. Similarly, Ni does not significantly affect the hardening provided by the Al3Sc precipitates, despite the presence of 0.14–0.17 at.% Ni in the Al3Sc nano-precipitates. The strengthening contributions of the Al3Ni and Al3Sc phases at ambient temperature are cumulative in the ternary alloys. For creep deformation at 300 °C, all alloys show a creep threshold stress, indicating that both types of precipitates impede dislocation motion. The ternary Al–Ni–Sc alloys show higher creep threshold stresses than their binary counterparts, also consistent with cumulative strengthening effects of precipitation strengthening (from Al3Sc nano-precipitates) and load transfer (from Al3Ni micro-fibers).

LanguageEnglish (US)
Pages334-346
Number of pages13
JournalActa Materialia
Volume164
DOIs
StatePublished - Feb 1 2019

Fingerprint

Scandium alloys
High strength alloys
Ternary alloys
Binary alloys
Strengthening (metal)
Nickel alloys
Solidification
Hardening
Precipitates
Aluminum alloys
Creep
Composite materials
Coarsening
Fibers
Eutectics
Aging of materials
Hardness

Keywords

  • Aluminum alloys
  • Atom probe tomography
  • Composites
  • Creep
  • Load transfer

ASJC Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Polymers and Plastics
  • Metals and Alloys

Cite this

Suwanpreecha, C. ; Toinin, J. Perrin ; Michi, R. A. ; Pandee, P. ; Dunand, David C ; Limmaneevichitr, C. / Strengthening mechanisms in Al–Ni–Sc alloys containing Al3Ni microfibers and Al3Sc nanoprecipitates. In: Acta Materialia. 2019 ; Vol. 164. pp. 334-346.
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abstract = "Dilute Al–Sc alloys (<0.4 wt{\%} Sc) are creep-resistant up to ∼300 °C owing to coherent, nanosize Al3Sc particles created by solid-state precipitation. By contrast, eutectic Al–Ni alloys (Al-6 wt.{\%} Ni) derive their high strength at elevated temperature from Al3Ni microfibers formed during solidification. Here, we investigate ternary Al–6Ni-0.2Sc and Al–6Ni-0.4Sc alloys with both types of strengthening precipitates (Al3Sc and Al3Ni) and compare them to binary Al–6Ni, Al-0.2Sc and Al-0.4Sc alloys with a single population of precipitates. Kinetics of Al3Sc and Al3Ni precipitation and coarsening are studied via hardness measurements during isochronal and isothermal aging; the two phases resist coarsening up to 475 and 350 °C, respectively, upon short term exposures (1 h isochronal steps). No noticeable effect of Sc is observed on the Al3Ni micro-fiber composition and hardening in the alloy. Similarly, Ni does not significantly affect the hardening provided by the Al3Sc precipitates, despite the presence of 0.14–0.17 at.{\%} Ni in the Al3Sc nano-precipitates. The strengthening contributions of the Al3Ni and Al3Sc phases at ambient temperature are cumulative in the ternary alloys. For creep deformation at 300 °C, all alloys show a creep threshold stress, indicating that both types of precipitates impede dislocation motion. The ternary Al–Ni–Sc alloys show higher creep threshold stresses than their binary counterparts, also consistent with cumulative strengthening effects of precipitation strengthening (from Al3Sc nano-precipitates) and load transfer (from Al3Ni micro-fibers).",
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Strengthening mechanisms in Al–Ni–Sc alloys containing Al3Ni microfibers and Al3Sc nanoprecipitates. / Suwanpreecha, C.; Toinin, J. Perrin; Michi, R. A.; Pandee, P.; Dunand, David C; Limmaneevichitr, C.

In: Acta Materialia, Vol. 164, 01.02.2019, p. 334-346.

Research output: Contribution to journalArticle

TY - JOUR

T1 - Strengthening mechanisms in Al–Ni–Sc alloys containing Al3Ni microfibers and Al3Sc nanoprecipitates

AU - Suwanpreecha, C.

AU - Toinin, J. Perrin

AU - Michi, R. A.

AU - Pandee, P.

AU - Dunand, David C

AU - Limmaneevichitr, C.

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N2 - Dilute Al–Sc alloys (<0.4 wt% Sc) are creep-resistant up to ∼300 °C owing to coherent, nanosize Al3Sc particles created by solid-state precipitation. By contrast, eutectic Al–Ni alloys (Al-6 wt.% Ni) derive their high strength at elevated temperature from Al3Ni microfibers formed during solidification. Here, we investigate ternary Al–6Ni-0.2Sc and Al–6Ni-0.4Sc alloys with both types of strengthening precipitates (Al3Sc and Al3Ni) and compare them to binary Al–6Ni, Al-0.2Sc and Al-0.4Sc alloys with a single population of precipitates. Kinetics of Al3Sc and Al3Ni precipitation and coarsening are studied via hardness measurements during isochronal and isothermal aging; the two phases resist coarsening up to 475 and 350 °C, respectively, upon short term exposures (1 h isochronal steps). No noticeable effect of Sc is observed on the Al3Ni micro-fiber composition and hardening in the alloy. Similarly, Ni does not significantly affect the hardening provided by the Al3Sc precipitates, despite the presence of 0.14–0.17 at.% Ni in the Al3Sc nano-precipitates. The strengthening contributions of the Al3Ni and Al3Sc phases at ambient temperature are cumulative in the ternary alloys. For creep deformation at 300 °C, all alloys show a creep threshold stress, indicating that both types of precipitates impede dislocation motion. The ternary Al–Ni–Sc alloys show higher creep threshold stresses than their binary counterparts, also consistent with cumulative strengthening effects of precipitation strengthening (from Al3Sc nano-precipitates) and load transfer (from Al3Ni micro-fibers).

AB - Dilute Al–Sc alloys (<0.4 wt% Sc) are creep-resistant up to ∼300 °C owing to coherent, nanosize Al3Sc particles created by solid-state precipitation. By contrast, eutectic Al–Ni alloys (Al-6 wt.% Ni) derive their high strength at elevated temperature from Al3Ni microfibers formed during solidification. Here, we investigate ternary Al–6Ni-0.2Sc and Al–6Ni-0.4Sc alloys with both types of strengthening precipitates (Al3Sc and Al3Ni) and compare them to binary Al–6Ni, Al-0.2Sc and Al-0.4Sc alloys with a single population of precipitates. Kinetics of Al3Sc and Al3Ni precipitation and coarsening are studied via hardness measurements during isochronal and isothermal aging; the two phases resist coarsening up to 475 and 350 °C, respectively, upon short term exposures (1 h isochronal steps). No noticeable effect of Sc is observed on the Al3Ni micro-fiber composition and hardening in the alloy. Similarly, Ni does not significantly affect the hardening provided by the Al3Sc precipitates, despite the presence of 0.14–0.17 at.% Ni in the Al3Sc nano-precipitates. The strengthening contributions of the Al3Ni and Al3Sc phases at ambient temperature are cumulative in the ternary alloys. For creep deformation at 300 °C, all alloys show a creep threshold stress, indicating that both types of precipitates impede dislocation motion. The ternary Al–Ni–Sc alloys show higher creep threshold stresses than their binary counterparts, also consistent with cumulative strengthening effects of precipitation strengthening (from Al3Sc nano-precipitates) and load transfer (from Al3Ni micro-fibers).

KW - Aluminum alloys

KW - Atom probe tomography

KW - Composites

KW - Creep

KW - Load transfer

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