Structural Similarities among Oxygen-Deficient Perovskites

Mark T. Anderson, John T. Vaughey, Kenneth R. Poeppelmeier*

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

161 Scopus citations

Abstract

A general review and description is given of vacancy patterns in oxygen-deficient perovskites AmBmO3m−x. Thirteen compounds that contain unique oxygen vacancy patterns and that adopt structures related to cubic closest packing are examined in detail: m = 2, x = 1, Ca2Mn2O5, LaSrCuGaO5, La2Ni2O5, LaSrCuAlO5, YBaCuFeO5, Ca2Co2O5; m = 3, x = 1, 2, or 3, LaBa2Cu2TaO8, LaSr2Fe3O8, YBa2Cu3O7, LnSr2Cu2GaO7, YBa2Cu3O6; m = 4, x = 1, Ba2La2Cu2Sn2O11 and Ca4Ti2Fe2O11. The structural similarity among the compounds is stressed by the presentation and examination of AO3−x slices. The influence of the A and B cations on the manner in which successive AO3−x layers are stacked is presented and discussed.

Original languageEnglish (US)
Pages (from-to)151-165
Number of pages15
JournalChemistry of Materials
Volume5
Issue number2
DOIs
StatePublished - 1993

ASJC Scopus subject areas

  • Chemistry(all)
  • Chemical Engineering(all)
  • Materials Chemistry

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